Kohtaro Osakada, Yasushi Nishihara Transmetalation of Boronic Acids and their Derivatives: Mechanistic Elucidation and Relevance to Catalysis Dalton Trans. 2022, 51, 777-796. Cover pictureに採用されました! |
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Kohtaro Osakada, Yoshitaka Tsuchido, Makoto Tanabe Multinuclear Pd and Pt complexes with bridging Si- and Ge-ligands. Stable and flexible coordination bonds and structures and reactions of the molecules Coord. Chem. Rev. 2020, 412, 213195. |
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小坂田耕太郎 有機金属錯体触媒を用いる重合反応「触媒技術の動向と展望2020」 触媒学会, 2020, 印刷中. |
Yusuke Yoshigoe, Yuji Suzaki, Kohtaro Osakada Cyclic Diplatinum Complex with a Tröger’s Base Ligand and Reductive Elimination of a Highly Strained Ring Molecule Zeitschrift für anorganische und allgemeine Chemie, 2021, 647, 1319–1325. |
Cover pictureに採用されました!
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Yuji Suzaki, Yugo Fukuchi, Hiroko Tadami, Take-aki Koizumi, Kohtaro Osakada, Tomohito Ide, Masaki Horie, Norihisa Hoshino, Tomoyuki Akutagawa Further Investigations of Crystal-to-Crystal Phase Transition of a [2]Pseudorotaxane Composed of Ferrocene-terminated Dialkylammonium and Dibenzo[24]crown-8-ether CrystEngComm, 2021, 23, 5944-5952. |
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Daisuke Takeuchi, Yoshiaki Tojo, Kohtaro Osakada Synthesis of a Ni Complex Chelated by a [2.2]Paracyclophane-Functionalized Diimine Ligand and Its Catalytic Activity for Olefin Oligomerization Molecules, 2021, 26, 2719. Special Issue: Ligand and Catalysis |
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Yasushi Nishihara, Yasuhiro Nishide, Kohtaro Osakada Synthesis and reactivity of boryloxorhodium complexes. Relevance to intermolecular transmetalation from boron to rhodium in Rh-catalyzed reactions Dalton Trans., 2021, 50, 3610-3615. |
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Daisuke Takeuchi, Makoto Nakamura, Kohtaro Osakada Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins Polym. Chem., 2021, 12, 299-306. |
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Yuji Suzaki, Yuhei Fujii, Kohtaro Osakada Cyclodextrin Rotaxanes of Pt Complexes and Their Conversion to Pt Nanoparticles Molecules, 2020, 25, 5617. |
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Yoshitaka Tsuchido, Ryota Abe, Tomohito Ide, Kohtaro Osakada A Macrocyclic Gold(I)‐biphenylene Complex: Triangular Molecular Structure with Twisted Au2(diphosphine) Corners and Reductive Elimination of [6]Cycloparaphenylene Angew. Chem. Int. Ed., 2020, 59, 22928-22932. |
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Takayoshi Yamada, Daisuke Takeuchi, Kohtaro Osakada, Ichiro Aratani Copolymerization of 1-Decene with Alkyl and Alkenyl Methacrylates Catalyzed by Palladium-Diimine Complexes J. Jpn. Petrol. Inst., 2020, 63, 282-288. |
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Yoshitaka Tsuchido, Kazuki Okuma, Kohtaro Osakada, Tomohito Ide Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor Organometallics, 2020, 39, 2565-2569. Cover pictureに採用されました! |
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Take-aki Koizumi, Yoshitaka Tsuchido, Tomohito Ide, Kohtaro Osakada Structure and properties of lantern‐shaped hexapalladium complexes with germylene and thiolate ligands [Pd6(μ-GePh2)(μ-SC6H4-p-X)(CN-C6H3Me2-2,6)8] (X = NO2, Cl, H, CH3) Eur. J. Inorg. Chem., 2020, 2253-2259. |
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Yuji Suzaki, Takashi Saito, Kohtaro Osakada Catalytic and stoichiometric reactions of Arylpalladium(II) complexes bearing a trans-chelating dinitrogen ligand with arylboronic acids J. Organomet. Chem. 2020, 910, 121088. |
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Yoshitaka Tsuchido, Atsushi Kanda, Kohtaro Osakada Gold(I) complexes with chloro(diaryl)silyl ligand. Stoichiometric reactions and catalysis for O-functionalization of organosilane Tetrahedron 2020, 76, 131076. |
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Daisuke Takeuchi, Karin Nakamura, Yuki Tokura, Ryuji Tsubamoto, Kohtaro Osakada Synthesis of Polycyclic Polyolefins by a Pd-catalyzed Isomerization Polymerization of Vinylcycloalkanes Polym. J. 2020, 52, 93-101. |
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Daisuke Takeuchi, Hiroyuki Takada, Kenji Yamazaki, Kohtaro Osakada Hydrovinylation of Olefins Catalyzed by RuCl2(MeCN)2(cod)/organoaluminum System Transactions of the Materials Research Society of Japan 2019, 44, 137-141. |
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Li Yi Tan, Daisuke Takeuchi, Kohtaro Osakada Synthesis of Poly(arylene alkenylene)s by Pd-catalyzed Three-component Coupling Polycondensation of Diiodoarenes, Non-conjugated dienes, and Nucleophiles Accompanying Chain Walking Isomerization J. Polym. Sci., Polym. Chem 2019, 57, 2535-2542. |
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Kenji Tsukamoto, Koji Takagi, Shusaku Nagano, Mitsuo Hara, Yutaka Ie, Kohtaro Osakada, Daisuke Takeuchi π-Extension of electron-accepting dithiarubicene with a cyano-substituted electron-withdrawing group and application in air-stable n-channel organic field effect transistors J. Mater. Chem. (C) 2019, 7, 12610-12618. |
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梅本叡史、徳満勝久、竹下宏樹、竹内大介、小坂田耕太郎 ポリオレフィン材料の低温力学物性と分子運動性に関する研究 材料(Journal of the Society of Materials Society, Japan) 2019, 68, 47-53. |
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Daisuke Takeuchi, Takayoshi Yamada, Yuichiro Nakamaru, Kohtaro Osakada, Ichihiro Aratani, Yutaka Suzuki Pd-Promoted Copolymerization of Methallyl and Isoprenyl Ethers and Acetate with α-Olefins Organometallics 2019, 38, 2323-2329. |
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Take-aki Koizumi, Kimiya Tanaka, Yoshitaka Tsuchido, Makoto Tanabe, Tomohito Ide, Kohtaro Osakada Bimolecular fusion of [Pd3(μ-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex Dalton Transactions 2019, 48, 7541-7545. |
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Li Yi Tan, Yoshitaka Tsuchido, Kohtaro Osakada, Zhengguo Cai, Yoshiaki Takahashi, Daisuke Takeuchi Synthesis and Aggregation Behavior of Poly(arylene alkenylene)s and Poly(arylene alkylene)s Having Dialkoxyphenylene and Aromatic Diimide Groups Macromolecules 2019, 52, 1642-1652. |
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Yuji Suzaki, Yuka Kobayashi, Yoshitaka Tsuchido, Kohtaro Osakada Pd-catalyzed Sonogashira coupling in aqueous media. Observation of micelles that contain substrates and catalyst Molecular Catalysis 2019, 466, 106-111. |
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Shinji Yamakawa, Daisuke Takeuchi, Kohtaro Osakada, Shigenaga Takano, Shojiro Kaita Copolymerization of 1,3-butadiene and norbornene catalyzed by Ni complexes [1] Reactive and Functional Polymers 2019, 136, 19-24. |
Daisuke Takeuchi, Takashi Iwasawa, Kohtaro Osakada Double-Decker-Type Dipalladium Catalysts for Copolymerization of Ethylene with Acrylic Anhydride Macromolecules 2018, 51, 5048-5054. |
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Yoshitaka Tsuchido, Ryota Abe, Megumi Kamono, Kimiya Tanaka, Makoto Tanabe, Kohtaro Osakada Hydrosilylation of Aromatic Aldehydes and Ketones Catalyzed by Mono- and Tri-nuclear Platinum(0) Complexes Bull. Chem. Soc. Jpn. 2018, 91, 858-864. |
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Hiroki Noda, Kimiya Tanaka, Makoto Tanabe, Kohtaro Osakada Cyclic Platina(borasiloxane)s and Platina(siloxane)s and Their Chemical Properties Organometallics 2018, 37, 22-29. |
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Shao-Chi Cheng, Kai-Jen Chen, Yuji Suzaki, Yoshitaka Tsuchido, Ting-Shen Kuo, Kohtaro Osakada, Masaki Horie Reversible Laser-Induced Bending of Pseudorotaxane Crystals J. Am. Chem. Soc. 2018, 140, 90-93. |
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Makoto Tanabe, Toshihiro Hagio, Kohtaro Osakada, Masashi Nakamura, Yuya Hayashi, Joji Ohshita Synthesis of 4,4-Dihydrodithienosilole and Its Unexpected Cyclodimerization Catalyzed by Ni and Pt Complexes Organometallics 2017, 36, 1974-1980. |
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Makoto Tanabe, Megumi Kamono, Kimiya Tanaka, Kohtaro Osakada Triangular Triplatinum Complex with Four Bridging Si Ligands: Dynamic Behavior of the Molecule and Catalysis Organometallics 2017, 36, 1929-1935. |
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Daisuke Takeuchi, Yuriko Chiba, Shigenaga Takano, Hideo Kurihara, Minoru Kobayashi, Kohtaro Osakada Ethylene Polymerization Catalyzed by Dinickel Complexes with a Double-Decker Structure Polym. Chem. 2017, in press. |
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Yuji Suzaki, Minetada Kiho, Kohtaro Osakada Fluoroalkylation of a Methyplatinum(II) Complex under Photoirradiation Organometallics 2017, 36, 1391-1397. |
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Gilbert Yu, Yuji Suzaki, Kohtaro Osakada Cationic and Neutral Rotaxanes Having Different Functional Groups in the Axle Molecule and Their Corrdination to Pt(II) Chem. Asian J. 2017, 12, 372-377. 同誌のinner coverに採用されました!! |
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Makoto Tanabe, Ryouhei Yumoto, Tetsuyuki Yamada, Tomoko Fukuta, Tsuyoshi Hoshino, Kohtaro Osakada, Tomoaki Tanase Planar PtPd3 Complex Stabilized by Three Bridging Silylene Ligands Chem. Eur. J. 2017, 23, 1386-1392. |
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Kai-Jen Chen, Ya-Ching Tsai, Yuji Suzaki, Kohtaro Osakada, Atsushi Miura, Masaki Horie Rapid and Reversible Photoinduced Switching of a Rotaxane Crystal Nat. Commun. 2016, 7, 13321. |
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Makoto Tanabe, Shunsuke Iwase, Kohtaro Osakada Nickel(0)-Catalyzed Polycondensation of Silafluorene: Control over Molecular Weight and Polymer Growth Mechanism Organometallics 2016, 35, 2557-2562. |
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Matthieu Jouffroy, Dominique Arnspach, Dominique Matt, Kohtaro Osakada, Daisuke Takeuchi Synthesis of Optical Active Polystyrene Catalyzed by Monophosphine Pd Complexes Angew. Chem. Int. Ed. 2016, 55, 8367-8370. |
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Hirotaka Endo, Yuji Suzaki, Motonori Komura, Kohtaro Osakada Bi- and Multilayered Assembly of Amphiphilic Pd(II) and Pt(II) Complexes with N-Alkyl-4,4'-bipyridinium Ligands Bull. Chem. Soc. Jpn. 2016, 89, 1069-1071. 同誌のselected paperに選出されました!! |
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Hiroyuki Nagai, Yuji Suzaki, Kohtaro Osakada Chemical Modification of a [2]Rotaxane Composed of Dithiacrown Ether and Dialkylammonium with Organic and Inorganic Compounds Chem. Lett. 2016, 45, 834-836. |
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Gilbert Yu, Yuji Suzaki, Kohtaro Osakada Ferrocene-Containing [1]-, [2]-, [3]- and [4]Rotaxanes Synthesized from a Common Precursor RSC Adv. 2016, 6, 41369-41375. |
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Makoto Tanabe, Shunsuke Iwase, Atsushi Takahashi, Kohtaro Osakada Tetramer and Polymer of 2, 7-Dialkoxy-9H-9-silafluorene Composed of Si Backbone and π-Stacked Biphenylene Groups Chem. Lett. 2016, 45, 394-396. |
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Shigenaga Takano, Daisuke Takeuchi, Kohtaro Osakada Olefin Polymerization Catalyzed by Double-Decker Dipalladium Complexes: Low Branched Poly(α-Olefin)s by Selective Insertion of the Monomer Molecule Chem. Eur. J. 2015, 21, 16209-16218. |
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Daisuke Takeuchi, Keisuke Watanabe, Kohtaro Osakada Synthesis of Polyketones Containing Substituted Six-Membered Rings via Pd-Catalyzed Copolymerization of Methylenecyclohexanes with Carbon Monoxide Macromolecules 2015, 48, 6745-6749. |
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Daisuke Takeuchi, Keisuke Watanabe, Kenji Sogo, Kohtaro Osakada Polymerization of Methylenecyclohexanes Catalyzed by Diimine-Pd Complex. Polymers Having trans- or cis-1,4- and trans-1,3-Cyclohexylene Groups Organometallics 2015, 34, 3007-3011. |
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Kimiya Tanaka, Megumi Kamono, Makoto Tanabe, Kohtaro Osakada Ring Expansion of Cyclic Triplatinum(0) Silylene Complexes Induced by Insertion of Alkyne into a Si-Pt Bond Organometallics 2015, 34, 2985-2990. |
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Yoshitaka Tsuchido, Tomohito Ide, Yuji Suzaki, Kohtaro Osakada 1,4-Selective Diels-Alder Reaction of 9,10-Diethynylanthracene with 3,6-Difluorobenzyne Bull. Chem. Soc. Jpn. 2015, 88, 821-823. |
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Kenya Motokuni, Daisuke Takeuchi, Kohtaro Osakada Cyclopolymerization of 1,6-Heptadienes and 1,6,11-Dodecatrienes Having Acyclic Substituents Catalyzed by Pd-diimine Complexes Polym. Bull. 2015, 72, 583-597. |
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Makoto Tanabe, Shumpei Omine, Naoko Ishikawa, Kohtaro Osakada, Yoshihiro Hayashi, Susumu Kawauchi Bond Formation and Coupling between Germyl and Bridging Germylene Ligands in Dinuclear Pd(I) Complexes Angew. Chem. Int. Ed. 2015, 54, 2679-2683. |
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Kenya Motokuni, Daisuke Takeuchi, Kohtaro Osakada Double Cyclizative Polymerization of Trienes Catalyzed by Pd Complexes. Combined Ring-forming and Chain-walking Reactions of the Growing End Polym. Chem. 2015, 6, 1248-1254.(back-side cover picture paper) |
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Yuji Suzaki, Masanori Shirokawa, Takeyoshi Yagyu, Kohtaro Osakada Synthesis and Reactions of Pd(II) Complexes with Aryl, Aroyl and Iminoaroyl Ligands. Insertion of CO and RNC into the Pd-Ar Bond and Intermolecular Coupling of the Ligands Eur. J. Inorg. Chem. 2014, 31, 421-429. |
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Shigenaga Takano, Daisuke Takeuchi, Kohtaro Osakada Ethylene Polymerization at High Temperatures Catalyzed by Double-decker-type Dinuclear Fe and Co Complexes: Dimer Effect on Stability of the Catalyst and Polydispersity of the Product Organometallics 2014, 33, 5316-5323. |
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Kenya Motokuni, Daisuke Takeuchi, Kohtaro Osakada Double Cyclopolymerization of Monoterminal Trienes Using Pd Catalysis. Polymers Containing Functionallized Cyclic Groups with a Regulated Sequence Macromolecules 2014, 47, 6522-6526. |
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Shigenaga Takano, Daisuke Takeuchi, Kohtaro Osakada, Norihisa Akamatsu, Atsushi Shishido Double-Decker Type Dipalladium Catalyst for Olefin Polymerization. Introduction of Acrylate Units into Main Chain of Branched Polyethylene Angew. Chem. Int. Ed. 2014, 53, 9246-9250. |
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Hiroyuki Nagai, Yuji Suzaki, and Kohtaro Osakada Thiacrown Ethers with Oxygen and Sulfur for Coordination. Formation of the Pd and Pt Complexes and Pseudorotaxane with Dialkylammonium Eur. J. Inorg. Chem. 2014, 26, 4376–4384. |
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Yusuke Yoshigoe, Yuji Suzaki, and Kohtaro Osakada Intermolecular Aryl Ligands Transfer of the Diarylplatinium(II) Complexes with a Cyclooctadiene Ligand Chem. Lett. 2014, 43, 1337-1339. |
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Gilbert Yu, Yuji Suzaki, Yujin Maekawa, Tomoko Abe, Kohtaro Osakada, and Toshiyuki Yokoi Silica Nanospheres Functionalized by Ferrocene-containing [2]Rotaxane Chem. Lett. 2014, 43, 935-955. (Special Issue: Coordination Programming) |
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Kimiya Tanaka, Makoto Tanabe, Tomohito Ide, and Kohtaro Osakada Cationic Hydridotriplatinum Complex with Bridging Germylene Ligands Organometallics 2014, 33, 2608-2612. |
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Yuji Suzaki, Takashi Saito, Tomohito Ide and Kohtaro Osakada Rhomboid-shaped Organic Host Molecule with Small Binding Space. Unsymmetrical and Symmetrical Inclusion of Halonium Ions Dalton Trans. 2014, 43, 6643-6649. |
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Makoto Tanabe, Kimiya Tanaka, Shumpei Omine, Kohtaro Osakada Triangular Triplatinum(0) Complex with Bridging Germylene Ligands. Insertion of Alkyne into the Pt‒Ge Bond Rather Than the Pt‒Pt Bond Chem. Commun. 2014, 50, 6839-6842. 同誌のback-side coverに採用されました!! |
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Ryohei Yamakado, Shin-ichi Matsuoka, Masato Suzuki, Daisuke Takeuchi, Hyuma Masu, Isao Azumaya and Koji Takagi Synthesis, Reaction, and Optical Properties of Cyclic Oligomers Bearing 9,10-Diphenylanthracene Based on an Aromatic Tertiary Amide Unit RSC Adv. 2014, 4, 6752-6760. |
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Yuji Suzaki, Hiroyuki Nagai, Kohtaro Osakada Diversity in Bonding of Dithiadibenzo[24]crown Ether. Reversible Formaton of Pseudorotaxane of Dibenzylammonium and Complexation with PdCl2 Chem. Lett. 2014, 43, 714-716. |
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Yoshitaka Tsuchido, Yuji Suzaki, Tomohito ide, Kohtaro Osakada Dynamic Properties of Molecular Tweezers with a Bis(2-hydroxyphenyl)pyrimidine Backbone Chem. Eur. J. 2014, 20, 4762-4771. |
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Shigenaga Takano, Yuji Takeuchi, Daisuke Takeuchi, Kohtaro Osakada Selective Formation of Ethyl- and/or Propyl-branched Oligoethylene Using Double-Decker Type Dinuclear Fe Complexes as the Catalyst Chem. Lett. 2013, 42, 465-467. |
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Daisuke Takeuchi, Yuriko Chiba, Shigenaga Takano, Kohtaro Osakada Double-Decker-Type Dinuclear Nickel Catalyst for Olefin Polymerization: Efficient Incorporation of Functional Co-monomers Angew. Chem., Int. Ed. 2013, 52, 12536–12540. 同誌のCover Pictureに採用されました!! |
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Yuji Suzaki, Hirotaka Endo, Takahiro Kojima, Kohtaro Osakada Amphiphilic ferrocenylated alkylpyridinium: the formation of micelles and hydrogels and their disaggregation induced by an external stimulus Dalton trans. 2013, 42, 16222-16230. |
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Toshiaki Taira, Yuji Suzaki, Kohtaro Osakada Metallohydrogel Formed from Amphiphilic Pd Complex and α-Cyclodextrin: Control of its Sol-gel Transition Chem. Lett. 2013, 42, 1062-1064. |
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Yuji Suzaki, Yusuke Yoshigoe, Kohtaro Osakada Cyclic and Linear Poly(Ferrocenylene Alkylene)s Synthesized from Addition-condensation Polymerization of Ferrocene with Aldehydes J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3627–3635. |
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Makoto Tanabe, Atsushi Takahashi, Tetsuyuki Yamada, Kohtaro Osakada Dipalladium Complexes with Bridging Monoalkyl or Monophenyl Silyl Ligands in the Solid State and in Solutions Organometallics 2013, 32, 1815–1820. |
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Makoto Tanabe, Atsushi Takahashi, Tomoko Fukuta, Kohtaro Osakada Nickel-Catalyzed Cyclopolymerization of Hexyl- and Phenylsilanes Organometallics 2013, 32, 1037–1043. 2013年2月の同誌論文のMost Read Articles(Top 7)にランクインされました! |
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Gilbert Yu, Yuji Suzaki, Tomoko Abe, Kohtaro Osakada Introduction of Ferrocene-containing [2]Rotaxanes onto Siloxane, Silsesquioxane and Polysiloxanes via Click Chemistry Dalton Trans. 2013, 42, 1476-1482. |
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