1996年の原著論文

穐田研究室



4. Ruimao Hua, Munetaka Akita, and Yoshihiko Moro-oka
Reduction of Diruthenium Bridging Vinylidene Species Cp2Ru2(m-C=CH2)(CO)(m-CO)(MeCN) by Hydrosilane Leading to a Vinyl Complex Cp2Ru2(m-CH=CH2)(CO)2(SiR3) and Vinylsilane: A Model System for Production of an Olefinic Product from a Vinylidene Intermediate
Inorg. Chim. Acta 1996, 250, 177 - 183.

3. Munetaka Akita, Ruimao Hua, Tomoharu Oku, and Yoshihiko Moro-oka
Conversion of A Diruthenium Bridging Methylene Complexes Cp2Ru2(m-CH2)(m-CO)(CO)2 into Methane: Reactivity of Silyl-m-methylene Intermediates Cp2Ru2(m-CH2)(SiR3)(X)(CO)2 (X= H, SiR3) Relevant to Catalytic CO Hydrogenation and Activation of Si-H, C-H, and C-Si Bonds.
Organometallics 1996, 15, 4162 - 4177.

2. Munetaka Akita, Ruimao Hua, Tomoharu Oku, and Yoshihiko Moro-oka
Deoxygenative Reduction of Diruthenium Carbonyl Complexes (h5-C5H4R)2Ru2(m-CO)(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (h5-C5H4R)2Ru2(m-CH2)n(m-CO)2-n(CO)2 (n= 1, 2; R= H, CH3)
Organometallics 1996, 15, 2548 - 2553.

1. Ruimao Hua, Munetaka Akita, and Yoshihiko Moro-oka
C-H and Si-C Bond Activation on Diruthenium Bridging Methylene Complexes: Evidence for Reversible Oxidative Addition of Si-C(sp3) Bonds.
J. Chem. Soc., Chem. Commun. 1996, 541 - 542.


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