Recent publications (2001)

Akita Group

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10. Kazuhiro Uehara, Shiro Hikichi and Munetaka Akita

Rational Synthesis and Reversible Metal-metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal-metal Bond, TpiPr2M-Co(CO)3L (M= Ni, Co, Fe, Mn; L= CO, PPh3)

Organometallics 2001, 20, 5002-5004. Reprint (pdf file)

9. Ken-ichiro Sugawara, Shiro Hikichi and Munetaka Akita

Dichloromethane Activation by Chlorochromium(II) Complexes with TpiPr2: Generation of an Electrophilic Cr-Methylene Species without the Action of an External Cl-Abstraction Reagent

Chem. Lett. 2001, 1094-1095.

8. Shiro Hikichi, Michito Yoshizawa, Yasuyuki Sasakura, Hidehito Komatsuzaki, Yoshihiko Moro-oka and Munetaka Akita

Structural Characterization and Intramolecular Aliphatic C-H Oxidation Ability of M(III)(m-O)2M(III) Complexes of Ni and Co with Hydrotris(3,5-diaklylpyrazolyl)borate Ligands TpMe2,X (X= Me, H, Br) and TpiPr2

Chemistry - A European Journal 2001, 7, 5011-5028..

7. Masato Kujime, Shiro Hikichi and Munetaka Akita

C- and N/O-bound Enolatopalladium Complexes with Hydrotrispyrazolylborato Ligands (TpR: R= iPr2 and Me2) Obtained via Dehydrative Condensation Between the Hydroxo Complexes, TpRPd(py)-OH, and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds
Organometallics 2001, 20, 4049-4060. Reprint (pdf file)

6. Nobuhiko Shirasawa, Trieu Thi Nguyet, Shiro Hikichi, Yoshihiko Moro-oka, and Munetaka Akita

Tetrahedral, Highly Coordinatively Unsaturated 14e(Fe) and 15e(Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (TpR'), TpR'M-R (M= Fe, Co, Ni)

Organometallics 2001, 20, 3582-3598. Reprint (pdf file)

5. Shukichi Tanaka and Munetaka Akita

[(m4-H)[Rh4(PNNP)2(CO)4]+ A Novel Hydride Bridging Mode.

Angew. Chem. Int. Ed. in Engl. 2001, 40, 2865-2867.

4. Munetaka Akita, Satoshi Kakuta, Shuichiro Sugimoto, Masako Terada, Masako Tanaka, and Yoshihiko Moro-oka
Nucleophilic Addition to the h2-Alkyne Ligand in [CpFe(CO)2(h2-R-CC-R)]+. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile

Organometallics 2001, 20, 2736 - 2750. Reprint (pdf file)

3. Munetaka Akita, Shuichiro Sugimoto, Hideki Hirakawa, Shin-ichi Kato, Masako Terada, Masako Tanaka, and Yoshihiko Moro-oka

Higher Nuclearity Fe,Ru-Mixed Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex, (h5-C5Me5)(CO)2Fe-CC-Fe(h5-C5Me5)(CO)2

Oganometallics 2001, 20, 1555 - 1568. Reprint(pdf file)

2. Munetaka Akita, Hideki Musashi, Sadahiro Nakanishi, and Yoshihiko Moro-oka
Photochemical C-H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp2Ru2(m-CH2)(m-CHR)(CO)2 (R= H, Me)

J. Organomet. Chem. 2001, 617-618, 254 - 260.

1. Munetaka Akita, Yoshiaki Takahashi, Shiro Hikichi and Yoshihiko Moro-oka

Synthesis and Dehydrative Condensation of Monomeric Hydroxoruthenium Complexes with Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPr2Ru(L2)-OH (L2= dppe, bipy)

Inorg. Chem. 2001, 40, 169 - 172.@Reprint(pdf file)


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