| 東京工業大学 資源化学研究所 スマート物質化学部門 |
大学院総合理工学研究科 化学環境学専攻 |
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小池 隆司 助教 |
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| 所属 ＆ 連絡先 | ||
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東京工業大学 資源化学研究所 スマート物質化学部門 住所：〒226-8503 横浜市緑区長津田町4259, R1-27
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受賞など
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| 研究テーマ | ||
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光触媒は光エネルギーを利用して通常では困難な化学プロセスを実現できる可能性をもっています。本研究では、均一系遷移金属光触媒の特異な反応性に注目し、高効率で高い選択性をもつ新しい触媒的分子変換反応の開発を目指しています。 専門：有機金属化学・分子触媒化学・有機合成化学 |
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| 論文リスト | ||
Sunlight-driven Synthesis of gamma-Diketones via Oxidative Coupling of Enamines with Silyl Enol Ethers Catalyzed by [Ru(bpy)3]2+ Chem. Commun., 2012, 48, 5355-5357. Color Change of Redox-active Organometallic Dithienylethene Complexes by Photochemical and Redox Processes Dyes and Pigments 2012, 92, 854-860. フォトクロミックオルガノメタリックス フォトクロミズムの新展開と光メカニカル機能材料（シーエムシー出版）2011, 47-53. Photo- and Electro-chromic Organometallics with Dithienylethene (DTE) Linker, L2CpM-DTE-MCpL2: Dually Stimuli-Responsive Molecular Switch Dalton Trans., 2011, 40, 10643-10657 (Dalton Trans. 40th anniversary issue). Making Organometallic Molecular Wire via Oxidative Ligand Coupling Dalton Trans., 2011, 40, 8089-8091. 3,5-Bis(diphenylphosphinoethyl)pyrazolate ligand (PNNPC2) and its dirhodium complexes: comparison with related quadridentate dinucleating diphenylphosphinomethyl (PNNPPy) and phthalazine derivatives (PNNPPh) Inorg. Chim. Acta 2011, 374, 489-498. (special issue dedicated to Prof. W. Kaim). Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects as Compared with the Pyrazolate Derivative (PNNPPy) Organometallics, 2010, 29, 6493−6502. Reversible, Fine Performance Tuning of Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments Eur. J. Inorg. Chem., 2010, 23, 3571-3575 . 2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene. Chem. Commun., 2010, 46, 4529-4531. Photochromic Organometallics with a Dithienylethene (DTE) Bridge, M-CC-DTE-CC-M [M= MCp*(dppe)]: Photoswitchable Molecular Wire (M= Fe) vs. Dual Photo- and Electro-chromism (M= Ru). Chem. Eur. J., 2010, 16, 4762-4776. Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+ Chem. Lett., 2009, 38, 166−167. 
Remarkable Switching Behavior of Bimodally Stimuli-responsive Photochromic Dithienylethenes with Redox-active Organometallic Attachements Chem. Commun. 2008, 5812-5814. Organometallic Chemistry of Polycarbon Species: From Clusters to Molecular Devices Dalton Trans. 2008, 3523-3530. (invited Perspective; cover) Aerobic Oxidation of Alcohols with Bifunctional Transition Metal Catalysts Bearing C-N Chelate Ligands Chem. Asian J., 2008, 3, 1479−1485. Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C-N Chelate Ligands Organometallics, 2008, 27, 2795−2802. Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes Angew. Chem. Int. Ed., 2008, 47, 2447-2449 (selected as "Very Important Papers"). Synthesis and Properties of Alkylruthenium Complexes Bearing Primary and Secondary Amine Ligands J. Organomet. Chem., 2007, 692, 408-419. Reaction of 16-Electron Ruthenium and Iridium Amide Complexes with Acidic Alcohols: Intramolecular C-H Bond Activation and the Isolation of Cyclometalated Complexes Organometallics, 2005, 24, 724-730. Mechanistic Aspects of Formation of Chiral Ruthenium Hydride Complexes from 16-Electron Ruthenium Amide Complexes and Formic Acid: Facile Reversible Decarboxylation and Carboxylation Adv. Synth. Catal., 2004, 346, 37-41. Stereoselective Synthesis of Optically Active α-Hydroxy Ketones and anti-1,2-Diols via Asymmetric Transfer Hydrogenation of Unsymmetrically Substituted 1,2-Diketones Org. Lett., 2000, 2, 3833-3836. |
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| その他 | ||
”動的”なピンサー型金属錯体：アルコールとアンモニアから第一級アミンをつくる！ 化学, 2009年4月号, 2009年の化学：注目の論文 | ||
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