II.　14族水素化物による有機金属化合物の還元反応

2. Munetaka Akita, Tomoharu Oku, Yoshihiko Moro-oka
Oxymethylation of Iron Complexes [CpFe(CO)2(R)] with HMMe3 [M = Sn, Si,; Cp = C5H5] leading to R-CH2OH via a Formylation-Hydrometalation Sequence
J. Chem. Soc., Chem. Commun. 1989, 1790 - 1792.

3. Munetaka Akita, Osamu Mitani, Masahiro Sayama, and Yoshihiko Moro-oka
Reduction of Acyl Ligand in Transition-Metal Complexes by Catalytic Hydrosilylation
Organometallics 1991, 10, 1394 - 1399.

4. Munetaka Akita, Tomoharu Oku, and Yoshihiko Moro-oka
Oxymethylation of Alkyliron Complex, CpFe(CO)2-R, with Hydrostannane and -silane Leading to R-CH2OH Derivatives : Its Related Reactions of CpFe(CO)(L)-R and CpFe(CO)(L)-C(O)R Type Organoiron Complexes and Molecular Structure of trans-CpFe(H)(CO)(SnPh3)2
Organometallics 1991, 10, 3080 - 3089.

5. Munetaka Akita, Tomoharu Oku, and Yoshihiko Moro-oka
One-step Transformation of a Coordinated CO into CH2 on Diruthenium Complexes by the Action of Hydrosilanes: a Model for the Fischer-Tropsch Mechanism
J. Chem. Soc., Chem. Commun. 1992, 1031 - 1032.

6. Munetaka Akita, Tomoharu Oku, Ruimao Hua, and Yoshihiko Moro-oka
Reduction of Ru and Fe m-Methylene Complexes with Hydrosilanes Producing Alkane: A Model System for Methanation via the Fischer-Tropsch Mechanism
J. Chem. Soc., Chem. Commun. 1993, 1670 - 1672.

7. Munetaka Akita, Kazumi Noda, and Yoshihiko Moro-oka
Formation of a Trinuclear m3-Methylidyne Complex, (m3-CH)[MoCp(CO)2]3, through Reduction of the CO Ligand in Cp2Mo2(CO)4 by a Hydrosilane
Organometallics 1994, 13, 4145-4147.

8. Munetaka Akita and Yoshihiko Moro-oka
An Organometallic Approach to Catalytic CO Hydrogenation
- Deoxygenative Reduction of Model Compounds by Hydrosilanes -
Stud. Surf. Sci. Cat. 1995, 92, 137 - 142.

9. Munetaka Akita, Kazumi Noda, Yoshiaki Takahashi, and Yoshihiko Moro-oka
Deoxygenative Reduction of Dimolybdenumcarbonyl Complexes Mo2(h5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear m3-Methylidyne and m3-Ethylidyne Complexes, (m3-CR)[Mo(h5-C5H4R')(CO)2]3, and Analysis of the Rotational Processes of the Mo(h5-C5H4R')(CO)2 Moieties
Organometallics 1995, 14, 5209 - 5220.

10. Ruimao Hua, Munetaka Akita, and Yoshihiko Moro-oka
C-H and Si-C Bond Activation on Diruthenium Bridging Methylene Complexes: Evidence for Reversible Oxidative Addition of Si-C(sp3) Bonds.
J. Chem. Soc., Chem. Commun. 1996, 541 - 542.

11. Munetaka Akita, Ruimao Hua, Tomoharu Oku, and Yoshihiko Moro-oka
Deoxygenative Reduction of Diruthenium Carbonyl Complexes (h5-C5H4R)2Ru2(m-CO)(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (h5-C5H4R)2Ru2(m-CH2)n(m-CO)2-n(CO)2 (n= 1, 2; R= H, CH3)
Organometallics 1996, 15, 2548 - 2553.

12. Ruimao Hua, Munetaka Akita, and Yoshihiko Moro-oka
Reduction of Diruthenium Bridging Vinylidene Species Cp2Ru2(m-C=CH2)(CO)(m-CO)(MeCN) by Hydrosilane Leading to a Vinyl Complex Cp2Ru2(m-CH=CH2)(CO)2(SiR3) and Vinylsilane: A Model System for Production of an Olefinic Product from a Vinylidene Intermediate
Inorg. Chim. Acta 1996, 250, 177 - 183.

13. Munetaka Akita, Ruimao Hua, Tomoharu Oku, and Yoshihiko Moro-oka
Conversion of A Diruthenium Bridging Methylene Complexes Cp2Ru2(m-CH2)(m-CO)(CO)2 into Methane: Reactivity of Silyl-m-methylene Intermediates Cp2Ru2(m-CH2)(SiR3)(X)(CO)2 (X= H, SiR3) Relevant to Catalytic CO Hydrogenation and Activation of Si-H, C-H, and C-Si Bonds,
Organometallics 1996, 15, 4162 - 4177.

14. Munetaka Akita, Ruimao Hua, Selby A. R. Knox, Yoshihiko Moro-oka, Sadahiro Nakanishi, and Michael I. Yates
Specific alkylidene coupling of the labile diruthenium bridging methylene complex, Cp2Ru2(m-CH2)(CO)2(MeCN), with diazoalkanes (N2=CR2) giving olefinic products
J. Chem. Soc. Chem. Commun., 1997, 51 - 52.

15. Munetaka Akita, Ruimao Hua, and Yoshihiko Moro-oka
Methylene - methylidyne-hydride interconversion on a tetraruthenium system
J. Organomet. Chem., 1997, 539, 205 - 207.

16. Munetaka Akita, Ruimao Hua, Sadahiro Nakanishi, Masako Tanaka, and Yoshihiko Moro-oka
Synthesis and Reactivity of Labile MeCN Adducts of Diruthenium Bis(m-methylene) Species, Cp2Ru2(m-CH2)2(CO)n(MeCN)2-n (n= 1, 2): Reaction with H-sources, H-X (X= SiR3, SnR3, H), and C-C Coupling with Alkyne and Diazoalkane.
Organometallics 1997, 16, 5572 - 5584.

17. Munetaka Akita, Ruimao Hua, Selby A. R. Knox, Yoshihiko Moro-oka, Sadahiro Nakanishi and Michael I. Yates
Specific C-C coupling of the labile diruthenium bridging methylene complex, Cp2Ru2(m-CH2)(CO)2(MeCN), with diazoalkanes (R2C=N2) leading to alkenyl complexes, Cp2Ru2(m-CH=CR2)(m-H)(CO)2, and alkenes, CH2=CR2
J. Organomet. Chem., 1998, 569, 71 - 83.

18. Munetaka Akita, Sadahiro Nakanishi, Hideki Musashi, and Yoshihiko Moro-oka
Photochemical C-H bond activation of the diruthenium bridging methylene complex, Cp2Ru2(m-CH2)2(CO)2: insertion of norbornadienes into the methylene C-H bond and unprecedented intramolecular H-D exchange between the two methylene units
J. Chem. Soc. Chem. Commun., 1999, 145-146.

19. Munetaka Akita, Hideki Musashi, Sadahiro Nakanishi, and Yoshihiko Moro-oka
Photochemical C-H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp2Ru2(m-CH2)(m-CHR)(CO)2 (R= H, Me)

J. Organomet. Chem. 2001, 617-618, 254 - 260.

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