V.　金属-金属結合を構造モチーフとしない多核金属錯体の研究

[(m4-H)[Rh4(PNNP)2(CO)4]+ [A Novel Hydride Bridging Mode.

Angew. Chem. Int. Ed. in Engl. 2001, 40, 2865-2867.

2. Shukichi Tanaka, Christian Dubs, Akiko Inagaki and Munetaka Akita

Tetranuclear Complexes Based on Dynamic Metal-metal Linkage, [(m4-X)Rh4(CO)4(PNNP)2]n+ [X / n= R-CｺC / 1 (Acetylide), C2 / 0 (Dicarbide)]

Organometallics, 2004, 23, 317 - 319.

3. Christian Dubs, Akiko Inagaki and Munetaka Akita
Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements: Proton-induced reversible metal migration on an iridium complex with a novel dinucleating PNNN ligand (3-diphenylphosphinomethyl-5-pyridylpyrazolate)
Chem. Commun. 2004, 2760 - 2761

4. Shukichi Tanaka, Christian Dubs, Akiko Inagaki and Munetaka Akita

Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M--M Interactions in [(m-X)Rh2(PNNP)(CO)2]n+ and [(m4-X)Rh4(PNNP)2(CO)4]n+ [X= H, O, CｺC-R, R-CｺC-R, CｺC, CH=CH2, SMe2; n= 0, 1: PNNP= 3,5-bis(diphenylphosphinomethyl)pyrazolato].

Organometallics 2005, 24, 163 - 184.

5. Christian Dubs, Toshiki Yamamoto, Akiko Inagaki, and Munetaka Akita

Synthesis of a Library of Ir-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(mu-BL)M'L']BF4, I.: Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements.

Organometallics 2006, 25, 1344 - 1358.
6. Christian Dubs, Toshiki Yamamoto, Akiko Inagaki, and Munetaka Akita

Synthesis of a Library of Ir-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(mu-BL)M'L']BF4, II.: Preparation, Basic Coordination Properties and Reactivity of the Carbonyl Complexes.

Organometallics 2006, 25, 1359 - 1367.

7. Christian Dubs, Toshiki Yamamoto, Akiko Inagaki, and Munetaka Akita

A New Method for the Conversion of Allyl Alcohol into pi-Allyl Species Promoted by Nucleophilic Interaction with a CO Ligand

Chem. Commun. 2006, 1962 - 1964.

8. Gou Higashihara, Akiko Inagaki and Munetaka Akita

Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments.

Dalton Trans. 2008, 1888.

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