穐田・吉沢研究室（錯体化学・超分子化学）

	Tokyo Institute of Technology, Institute of Innovative Research, Laboratory for Chemistry and Life Science
	Interdisciplinary Graduate School of Science Engineering Department of Environmental Chemistry Engineering

Yuya Tanaka

Assistant Professor

Y.T.

　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　

Affiliation & Address
	Laboratory for Chemistry and Life Science Institute of Innovative Research Tokyo Institute of Technology Address：4259-R1-27, Nagatsuta, Midori-ku, Yokohama 226-8503, Japan Phone：+81-45-924-5229　Fax：+81-45-924-5230 E-mail：ytanaka@res.titech.ac.jp
Profile
	(B. 1983.3.12) 2005.3　B.S.　Tokyo Institute of Technology　　　　　　　　　　　　　　　　 2007.3　M.S.　Tokyo Institute of Technology 2010.3　Ph.D.　Tokyo Institute of Technology (2007.9ー2008.3　Universite´ de Rennes 1, C. Lapinte lab, France) (2008.4ー2010.3　JSPS Fellow DC2) 2010.6-2012.3　Postdoctoral Fellow, The University of Hong Kong (V. W. W. Yam Lab., Hong Kong) 2012.4-2012.12　JSPS Postdoctoral Fellow, Tokyo Institute of Technology (Ueno lab) 2013.1-present　Assistant Professor, Tokyo Institute of Technology
Recent Publications
	H. Wagata,* G. Harada, E. Nakashima, M. Asaga, T. Watanabe, Y. Tanaka, M. Tada, K. Yubuta Formation of Double-Cone-Shaped ZnO Mesocrystals by Addition of Ethylene Glycol to ZnO Dissolved Choline Chloride-Urea Deep Eutectic Solvents and Observation of Their Manners of Growth CrystEngComm, 2021, in press.(DOI: 10.1039/D1CE01049B) H. Komatsuzaki,* K. Ohira, S. Tadokoro, Y. Yamasaki, H. Oouchi, M. Satoh, T. Agou, Y. Tanaka, M. Akita, J. Nakazawa, S. Hikichi Synthesis, structural characterization, and reactivity of a dinuclear cobalt(II) (μ-hydroxo) (μ-pyrazolato) complex based on a hydrotris(pyrazolyl)borate ligand Inorg. Chim. Acta, 2021, 570, 120533.(DOI: 10.1016/j.ica.2021.120533) S. Ogawa, S. Chattopadhyay, Y. Tanaka,* T. Ohto, T. Tada, H. Tada, S. Fujii, T. Nishino, M. Akita* Control of Dominant Conduction Orbitals by Peripheral Substituents in Paddle-Wheel Diruthenium Alkynyl Molecular Junctions Chem. Sci. 2021, 12, 10871-10877.(DOI: 10.1039/D1SC02407H) L. Catti, H. Narita, Y. Tanaka, H. Sakai,* T. Hasobe, N. V. Tkachenko,* M. Yoshizawa* Supramolecular Singlet Fission of Pentacene Dimers within Polyaromatic Capsules J. Am. Chem. Soc. 2021, 143, 9361-9367. R. Sumida, Y. Tanaka, K. Niki, Y. Sei, S. Toyota, M. Yoshizawa* Cyclic Monoterpenes Trapped in a Polyaromatic Capsule: Unusual Selectivity, Isomerization, and Volatility Suppression Chem. Sci. 2021, 12, 9946-9951. A. Yashiro, Y. Tanaka,* T. Tada, S. Fujii, T. Nishino, M. Akita* Organometallic Molecular Wires with Thioacetylene Backbones, trans-{RS-(C≡C)n}2Ru(phosphine)4: High Conductance Through Non-Aromatic Bridging Linkers Chem. Eur. J. 2021, 27, 9666-9673. Y. Tanaka,* Y. Kato, K Sugimoto., R. Kawano, T. Tada, S. Fujii, M. Kiguchi, M. Akita* Single-Molecule Junction of Multinuclear Organometallic Wires: Long-Range Carrier Transport Brought About by Metal-Metal Interaction Chem. Sci. 2021, 12, 4338-4344 (DOI: 10.1039/D0SC06613C). Selected as a back cover art. K. Mishiba,* Y. Tanaka,* M. Akita* Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers Chem. Eur. J. 2020, 26, in press (DOI: 10.1002/chem.202004744). Selected as an inside cover art. M. Osawa,* S. Soma, M. Hoshino, Y. Tanaka, M. Akita Photoluminescent properties and molecular structures of dinuclear gold(I) complexes with bridged diphosphine ligands: near-unity phosphorescence from 3XMMCT/3MC Dalton. Trans. 2020, 49, 15204-15212. Y. Tanaka, K. Ohmura, S. Fujii, T. Tada, M. Kiguchi, M. Akita Single-Molecule Junction of a Cationic Rh(III) Polyyne Molecular Wire Inorg. Chem., 2020, 59, 13254-13261. Selected as a supprementary cover art. N. Kishida, K. Matsumoto, Y. Tanaka, M. Akita, H. Sakurai, M. Yoshizawa Anisotropic Contraction of a Polyaromatic Capsule and its Cavity-induced Compression Effect J. Am. Chem. Soc., 2020, 142, 9599-9603. H. Dobashi, L. Catti, Y. Tanaka, M. Akita, M. Yoshizawa N-Doping of Polyaromatic Capsules: Small Cavity Modification Leads to Large Change in Host-Guest Interactions Angew. Chem. Int. Ed., 2020, 59, 11881-11885. Y. Matsushita, R. Ochi, Y. Tanaka, T. Koike, M. Akita Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis Org. Chem. Front., 2020, 7, 1243-1248. M. Yamashina, Y. Tanaka, R. Lavendomme, T. K. Ronson, M. Pittelkow, J. R. Nitschke An antiaromatic-walled nanospace Nature, 2019, 574, 511-515. M. Osawa, H. Yamayoshi, M. Hoshino, Y. Tanaka, M. Akita Luminescence color alteration induced by trapped solvent molecules in crystals of tetrahedral gold(I) complexes: near-unity luminescence mixed with thermally activated delayed fluorescence and phosphorescence Dalton Trans., 2019, 48, 9094-9013. Y. Oyama, R. Kawano, Y. Tanaka, M. Akita Dinuclear Ruthenium Acetylide Complexes with Diethynylated Anthrahydroquinone and Anthraquinone Frameworks: A Multi-Stimuli-Responsive Organometallic Switch Dalton Trans., 2019, 48, 7432-7441. (New Talent: Asia Pacific themed issue) K. Matsumoto, S. Kusaba, Y. Tanaka, Y. Sei, M. Akita, K. Aritani, M. Haga, M. Yoshizawa A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted Fullerene Dimer Angew. Chem. Int. Ed., 2019, 58, 8463-8467. Y. Tanaka, M. Akita Organometallic Radicals of Iron and Ruthenium: Similarities and Dissimilarities of Radical Reactivity and Charge Delocalization Coord. Chem. Rev., 2019, 388, 334-342. (a special issue dedicated to Prof. Pombeiro) K. Kuroda, K. Yazaki, Y. Tanaka, M. Akita, H. Sakai, T. Hasobe, N. V. Tkachenko, M. Yoshizawa A Pentacene-based Nanotube Displaying Enriched Electro/Photochemical Activities Angew. Chem. Int. Ed., 2019, 58, 1115-1119. S. Agake, H. Komatsuzaki, M. Satoh, T. Agou, Y. Tanaka, M. Akita, J. Nakazawa, S. Hikichi A Monomeric Manganese(II) Catecholato Complex: Synthesis, Crystal Structure, and Reactivity toward Molecular Oxygen Inorg. Chim. Acta, 2019, 484, 424-429. Y. Tanaka, M. Akita Synthesis and Intramolecular Electronic Interactions of Hexaarylbenzene Bearing Redox-Active Cp(dppe)Fe-C≡C- Termini J. Organomet. Chem., 2018, 878, 30-37. (a special issue dedicated to Prof. Pombeiro) N. Noto, Y. Tanaka, T. Koike, M. Akita Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation ACS Catal., 2018, 8, 9408-9419. S. Agake, H. Komatsuzaki, M. Satoh, T. Agou, Y. Tanaka, M. Akita, J. Nakazawa, S. Hikichi A Monomeric Manganese(II) Catecholato Complex: Synthesis, Crystal Structure, and Reactivity toward Molecular Oxygen Inorg. Chim. Acta, 2018, in press. Y. Tanaka, M. Ono, M. Akita An Organometallic Molecular Wire Bearing A Manganese Porphyrin Linker: Coordination-Driven Modulation of the Metal-Metal Interaction Chem. Lett., 2018, 47, 1296-1299. Y. Tanaka, Y. Kato, T. Tada, S. Fujii, M. Kiguchi, M. Akita “Doping” of Polyyne with An Organometallic Fragment Leads to Highly Conductive Metallapolyyne Molecular Wire J. Am. Chem. Soc., 2018, 140, 10080-10084. M. Osawa, M. Aino, T. Nagakura, M. Hoshino, Y. Tanaka, M. Akita Near-unity thermally activated delayed fluorescence efficiency in three- and fourcoordinate Au(I) complexes with diphosphine ligands Dalton Trans., 2018, 47, 8229-8239.　Selected as an Inside Cover* K. Sugimoto, H. Idei, Y. Tanaka, M. Akita Synthesis and Charge Delocalization Property of Multimetallic Molecular Wires with Diethynylthiophene Bridges J. Organomet. Chem., 2017, 847, 121-131.　*Selected as a Front Cover art.* Y. Tanaka, M. Kiguchi, M. Akita Inorganic and Organometallic Molecular Wires for Single-Molecule Devices Chem. Eur. J., 2017, 23, 4741-4749. *Selected as a Front Cover art. Cover Profile ld at. 4740* K. Mishiba, M. Ono, Y. Tanaka, M. Akita A Fully Charge-Delocalized 2-Dimensional Porphyrin System with Two Different Class III States Chem. Eur. J., 2017, 23, 2067-2076. *Selected as an Inside Back Cover art.* K. Yazaki, S. Noda, Y. Tanaka, Y. Sei, M. Akita, M. Yoshizawa An M2L4 Molecular Capsule with a Redox Switchable Polyradical Shell Angew. Chem. Int. Ed., 2016, 55, 15031-15034. K. Sugimoto, Y. Tanaka, S. Fujii, T. Tada, M. Kiguchi, M. Akita Organometallic Molecular Wires as Versatile Modules for Energy-Level Alignment of the Metal-Molecule-Metal Junction Chem. Commun, 2016, 52, 5796-5799. *Selected as a Back Cover art.* K. Fujita, Y. Tanaka, S. Abe, T. Ueno A Photoactive Carbon-Monoxide-Releasing Protein Cage for Dose-Regulated Delivery in Living Cells Angew. Chem. Int. Ed., 2016, 55, 1056-1060. A. K.-W. Chan, W. H. Lam, Y. Tanaka, K. M.-C. Wong, V, W.-W. Yam Multiaddressable Molecular Rectangles with Reversible Host-guest Interactions: Modulation of pH-Controlled Guest Release and Capture Proc. Natl. Acad. Sci. USA, 2015, 112, 690-695. Y. Tanaka, K. Ono, M. Akita Synthesis and Wire-like Performance of Diruthenium Molecular Wire with a C≡C-Porphyrin-C≡C Linker J. Porphyrins Phthalocyanines, 2015, 19, 442-450.(a special issue for Prof. S. Fukuzumi) Y. Tanaka, T. Ishisaka, T. Koike, M. Akita Synthesis and Properties of Diiron Complexes with Heteroaromatic Linkers: An Approach for Modulation of Organometallic Molecular Wire Polyhedron, 2015, 86, 105-110. (a special issue for Prof. C. Lapinte) K. Fujita, Y. Tanaka, T. Sho, S. Ozeki, S. Abe, T. Hikage, T. Kuchimaru, S. Kizaka-Kondoh, T. Ueno Intracellular CO Release from Composite of Ferritin and Ruthenium Carbonyl Complexes J. Am. Chem. Soc., 2014, 136, 16902-16908. Y. Tanaka, K. M.-C. Wong, V. W.-W. Yam Double-Decker Type Platinum-Based Phosphorescent Tweezers － A Strategy for Extended Heterologous Metal-Metal Interactions Angew. Chem. Int. Ed., 2013, 52, 14117-14120. T. Ueno, H. Tabe, Y. Tanaka Artificial Metalloenzymes Constructed From Hierarchically-Assembled Proteins Chem. Asian J., 2013, 8, 1646－1660. Y. Tanaka, K. M.-C. Wong, V. W.-W. Yam Host－Guest Interactions of Phosphorescent Molecular Tweezers Based on an Alkynylplatinum(II) Terpyridine System with Polyaromatic Hydrocarbons Chem. Eur. J., 2013, 19, 390-399. 　 Y. Tanaka, K. M.-C. Wong, V. W.-W. Yam Phosphorescent molecular tweezers based on alkynylplatinum(II) terpyridine system: turning on of NIR emission via heterologous PtM interactions (M = PtII, PdII, AuIII and AuI) Chem. Sci., 2012, 3, 1185-1191. K. Johno, Y. Tanaka, T. Koike, M. Akita Making Organometallic Molecular Wire via Oxidative Ligand Coupling Dalton Trans., 2011, 40, 8089-8091. Y. Tanaka, T. Koike, M. Akita Reversible, Fine Performance Tuning of Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments Eur. J. Inorg. Chem., 2010, 23, 3571-3575. Y. Tanaka, T. Koike, M. Akita 2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene Chem. Commun., 2010, 46, 4529-4531. Y. Tanaka, T. Ishisaka, A. Inagaki, T. Koike, C. Lapinte, M. Akita Photochromic Organometallics with a Dithienylethene (DTE) Bridge, Y-C≡C-DTE-C≡C-Y [Y = MCp^(dppe)]: Photoswitchable Molecular Wire (M = Fe) vs. Dual Photo- and Electro-chromism (M = Ru) Chem. Eur. J., 2010, 16, 4762-4776. (Highlighted as Cover Picture) Y. Tanaka, J. A. Shaw-Taberlet, F. Justaud, O. Cador, T. Roisnel, M. Akita, J.-R. Hamon, C. Lapinte Electronic and Magnetic Couplings in Free and π-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp^(dppe)Fe]ⁿ⁺ (n = 0, 1) units Organometallics, 2009, 28, 4656-4669. Y. Matsuura, Y. Tanaka, M. Akita p-Diethynylbenzene-based Molecular Wires, Fe-C≡C-p-C₆H₂X₂-C≡C-Fe [Fe = Fe(η⁵-C⁵Me⁵)(dppe)]: Synthesis, Substituent Effects and Unexpected Formation of Benzodifuran J. Organomet. Chem., 2009, 694, 1840-1847 Y. Tanaka, T. Ozawa, A. Inagaki, M. Akita Redox-active Polyiron Complexes with Tetra(ethynylphenyl)ethene and [2,2]Paracyclophane Spacers Containing Ethynylphenyl Units: Extension to Higher Dimensional Molecule Dalton Trans., 2007, 928-933. (Highlighted as Hot Article) Y. Tanaka, A. Inagaki, M. Akita A Photoswitchable Molecular Wire with the Dithienylethene (DTE) Linker, (dppe)(η⁵-C⁵Me⁵)Fe-C≡C-DTE-C≡C-Fe(η⁵-C⁵Me⁵)(dppe) Chem. Commun., 2007, 1169-1171. M. Akita, Y. Tanaka, C. Naitoh, T. Ozawa, N. Hayashi, M. Takeshita, A. Inagaki, M.-C. Chung Synthesis of a Series of Diiron Complexes Based on Tetraethynylethene Skeleton and Related C6-endiyne Spacers, (dppe)Cp^Fe-C≡C-C(R)=C(R)-C≡C-FeCp^(dppe): Tunable Molecular Wires Organometallics, 2006, 25, 5261-5275.
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