Publication List

2010年

総説等

• 竹内大介，小坂田耕太郎
  ジエン，シクロオレフィンの異性化重合制御―新しい高分子の合成と集合機能―
  高分子, 59巻, 10月号, 794ページ（2010年）
• 中沢 浩 (編さん), 小坂田 耕太郎 (編さん)
  有機金属化学 (錯体化学会選書 6)
  三共出版 (2010年10月)
• 竹内大介
  グローイングポリマー「一山当てよう！」
  高分子, 59巻, 5月号, 312ページ（2010年）
• Makoto Tanabe, Kohtaro Osakada
  Sila- and Germametallacycles of Late Transition Metals
  Organometallics 2010, 29, 4702–4710.
• 竹内　大介
  パラジウム錯体触媒によるチェーンウォーキング重合―側鎖官能基分布の完全に制御された新しい高分子合成法―
  化学と工業，63巻，6月号，490ページ（2010年）
• 平　敏彰
  錯体化学会学生講演賞受賞レビュー　1Fa-17
  両親媒性Pd錯体とシクロデキストリンとの反応によるロタキサン及びヒドロゲル形成
  Bull. Jpn. Soc. Coord. Chem. 2010, 55, 88–90.
• 福田　智子
  錯体化学会ポスター受賞レビュー　1PD-015
  平面構造パラジウム四核錯体への金属フラグメントの付加と動的挙動
  Bull. Jpn. Soc. Coord. Chem. 2010, 55, 117–118.

原著論文

• Takeshi Okada, Daisuke Takeuchi, Kohtaro Osakada
  Cyclopolymerization of Monoterminal 1,6-Dienes Catalyzed by Pd Complexes
  Macromolecules 2010, 43, 7998–8006.
• Yeap Guan Yeow, Lee Huey Charn, Wan Ahmad Kamil Mahmood, Corrie T Imrie, Daisuke Takeuchi, Kohtaro Osakada
  Synthesis, Thermal and Optical Behaviour of Non-symmetric Liquid Crystal Dimers (4-Benzylidene-substituted-aniline-4-oxy)-pentyl-4-(4-phenyl)benzoateoxy]-hexane
  Phase Transactions 2010, 84, 29–37.
• Yuji Suzaki, Atsuko Takagi, Kohtaro Osakada
  Synthesis, Structure and Properties of the Macrocyclic Ferrocenophanes with Cyclopentadienyl Ligands Tethered by Oligo(ethylene glycol) Chain
  J. Organomet. Chem. 2010, 695, 2512–2518.
• Makoto Tanabe, Masaya Hanzawa, and Kohtaro Osakada
  Preparation and Thermal Reaction of Tetrastannapalladacyclopentane. Sn–Sn Bond Formation and Cleavage
  Organometallics, 2010, 29, 3535–3540.
• Sehoon Park, Takeshi Okada, Daisuke Takeuchi, Kohtaro Osakada
  Cyclopolymerization and Copolymerization of Functionalized 1,6-Heptadienes Catalyzed by Pd Complexes. Mechanism and Application to Physical Gel Formation
  Chem. Eur. J. 2010, in press (Very Important Paper, Cover Picture Paper).
• Neli Mintcheva, Makoto Tanabe, Kohtaro Osakada, Ivelina Georgieva, Tzvetan Mihailov, Natasha Trendafilova
  Synthesis and Characterization of a Dinuclear Platinum Complex with Silsesquioxanate Ligand
  J. Organomet. Chem. 2010, 695, 1738–1743.
• Toshiaki Taira, Yuji Suzaki, Kohtaro Osakada
  Hydrogel Composed of Organic Amphiphiles and α-Cyclodextrin. Supramolecular Network of Their Pseudorotaxanes in Aqueous Media
  Chem. Eur. J. 2010, 16, 6518–6529.
• Yuji Suzaki, Atsuko Takagi, Kohtaro Osakada
  Disaggregation Reaction of [2]Pseudorotaxanes Composed of Dibenzo[24]crown-8 and Dialkylammonium Having Isopropyl End Groups
  Chem. Lett. 2010, 39, 510–512.
• Yuji Suzaki, Toshiaki Taira, Kohtaro Osakada
  Reversible Formation and Destruction of Micelles of Amphiphilic Compounds in Aqueous Media. Competition with Pseudorotaxane Formation
  Bull. Chem. Soc. Jpn. 2010, 83, 378–384.
• Satoru Kuramochi, Yo-hei Kido, Synsuke Shioda, Makoto Minato, Masaki Kakeya, Kohtaro Osakada
  Reactions of Molybdenum Tetrahydrido Complex with Halohydrosilanes
  Bull. Chem. Soc. Jpn. 2010, 83, 165–169.

2009年

総説等

• 須崎裕司，小坂田耕太郎(共著)
  「超分子サイエンス」　第一章　超分子サイエンスの基礎，第3節　6. ロタキサン，カテナンの合成
  シーエムシー出版，2009
• Daisuke Takeuchi
  Recent Progress in Olefin Polymerization Catalyzed by Transition Metal Complexes. New Catalysts and New Reactions
  Dalton Trans 2009, 311-328 (Perspective).

原著論文

• Toshiaki Taira, Yuji Suzaki, Kohtaro Osakada
  Thermosensitive Hydrogels Composed of Cyclodextrin Pseudorotaxanes. Role of [3]Pseudorotaxane in the Gel Formation
  Chem. Commun. 2009, 7027-7029.
• Yuji Suzaki, Eriko Chihara, Atsuko Takagi, Kohtaro Osakada
  Rotaxanes of a Macrocyclic Ferrocenophane with Dialkylammonium Axle Components
  Dalton Trans 2009, 9881-9891.
• Makoto Tanabe, Masaya Hanzawa, Naoko Ishikawa, Kohtaro Osakada
  Formation and Ring Expansion of Germaplatinacycles via Dehydrogenative Ge−Ge and Ge−Pt Bond-Forming Reactions
  Organometallics 2009, 28, 6014-6019.
• Daisuke Takeuchi, Ryuichi Matsuura, Yusuke Fukuda, Kohtaro Osakada,
  Selective Cyclopolymerization of α,ω-Dienes and Copolymerization with Ethylene Catalyzed by Fe and Co Complexes
  Dalton Trans. 2009, 8955-8962.
• Makoto Minato, Gosuke Kikutsuji, Masaki Kakeya, Kohtaro Osakada, Mikio Yamasaki
  Reaction of Isocyanides with a Molybdenum Complex Containing a Tridentate Silyl-phosphine Ligand: the Si Ligand Effect on Site Preference of the Isocyanide Ligands
  Dalton Trans. 2009, 7684-7687.
• Daisuke Takeuchi, Yusuke Fukuda, Sehoon Park, Kohtaro Osakada
  Cyclopolymerization of 9,9-Diallylfluorene Promoted by Ni Complexes. Stereoselective Formation of Six- and Five-Membered Rings during the Polymer Growth
  Macromolecules 2009, 42, 5909-5912.
• Guan Yeow Yeap, Tiang-Chuan Hng, Daisuke Takeuchi, Kohtaro Osakada, Wan Ahmad Kamil Mahmood, Masato M. Ito
  Non-Cymmetric Liquid Crystal Dimers: High Thermal Stability in Nematic Phase Enhanced by Thiophene-2-Carboxylate Moiety
  Mo. Cryst. Liq. Cryst. 2009, 506, 134-139.
• Takeshi Okada, Daisuke Takeuchi, Atsushi Shishido, Tomiki Ikeda and Kohtaro Osakada
  Isomerization Polymerization of 4-Alkylcyclopentenes Catalyzed by Pd Complexes: Hydrocarbon Polymers with Isotactic-Type Stereochemistry and Liquid-Crystalline Properties
  J. Am. Chem. Soc. 2009, 131, 10852-10853.
• Junpei Kuwabara, Daisuke Takeuhi, and Kohtaro Osakada
  Structures of Co, Pd and Ni Complexes with Iminopyridine Ligands Having a Hydroxymethyl or Acrylate Pendant Group
  Polyhedron 2009, 28, 2459-2465.
• Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, Munetaka Akita, Daiki Monguchi, and Atsunori Mori
  Electrophilic Substitution of Thiophenes with Arylpalladium(II) and Platinum(II) Complex: Mechanistic Studies on Palladium-catalyzed CH Arylation of Thiophenes
  Bull. Chem. Soc. Jpn., 2009, 82, 555-562. (BCSJ Award Article)
• Masaki Kakeya, Makoto Tanabe, Yoshiyuki Nakamura, and Kohtaro Osakada
  Dialkyl- and diaryl-platinum(II) complexes with secondary phosphines. Preparation, structure and thermal reaction giving the metallopolymer
  J. Organomet. Chem. 2009, 694, 2270-2278.
• Yuji Suzaki, Shintaro Murata, and Kohtaro Osakada
  Ferrocene-containing Side Chain Polyrotaxanes Obtained by Radical Copolymerization of Styrenes with Acrylamide with a [2]Rotaxane Structure
  Chem. Lett. 2009, 38, 356-357.
• Yasushi Nishihara, Miwa Takemura, and Kohtaro Osakada
  Comparative Reactivity of Triorganosilanes, HSi(OEt)₃ and HSiEt₃, with IrCl(CO)(PPh₃)₂. Formation of IrCl(H)₂(CO)(PPh₃)₂ or Ir(H)₂(SiEt₃)(CO)(PPh₃)₂ Depending on the Substituents at Si
  Inorg. Chim. Acta 2009, 362, 2951-2956.
• Tetsuyuki Yamada, Akane Mawatari, Makoto Tanabe, Kohtaro Osakada, and Tomoaki Tanase
  Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands
  Angew. Chem., Int. Ed. 2009, 48, 568-571.
• Tatsuaki Sakano, Masaki Okano, Kohtaro Osakada
  Preparation of Triazole-furnished Ferrocene Derivatives and their PolymerComplexes of Silver(I)
  J. Inorg. Organomet. Polym. Mater. 2009, 19, 35-45 (Dedicated to Professor Takakazu Yamamoto).
• Daisuke Takeuchi, Akihisa Inoue, Fujio Ishimaru, and Kohtaro Osakada
  Polymerization and Copolymerization of Functionalized
  2-Alkoxy-1-methylenecyclopropanes to Form New Polymers Having Alkoxy Substituents
  J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 959-972.

2008年

総説等

• Yuji Suzaki, Toshiaki Taira, Kohtaro Osakada and Masaki Horie
  Rotaxanes and pseudorotaxanes with Fe-, Pd- and Pt-containing axles. Molecular motion in the solid state and aggregation in solution
  Dalton Trans. (Perspective) 2008, 4823-4833.
  (cover picture paper, 9月2日, Dalton Transactions のNews 欄で紹介)
  2008年9月の同誌論文のウエブによるアクセス第2位
• Daisuke Takeuchi, Kohtaro Osakada,
  New Polymerization of Dienes and Related Monomers Catalyzed byTransition Metal Complexes
  Polymer (Feature Article) 2008, 49, 4911-4924. (cover picture paper)
• 竹内大介，小坂田耕太郎
  後期遷移金属触媒を用いるジエンの新しい高分子合成
  日本ゴム協会誌，2008, 81, 419-423.
• 小坂田耕太郎，竹内大介
  「後期遷移金属錯体触媒によるオレフィン重合と共重合 」
  次世代ポリオレフィン総合研究，Vol. 1, p. 120-129，次世代ポリオレフィン総合研究会編，三恵社，2008.

原著論文

• Makoto Tanabe, Naoko Ishikawa, Masaya Hanzawa, Kohtaro Osakada
  Mono- and Dinuclear Germapalladacycles Obtained via the Ge-Ge Bond Forming Reactions Promoted by Pd Complexes
  Organometallics 2008, 27, 5152-5158.
• Daisuke Takeuchi, Ryuichi Matsuura, Kohtaro Osakada
  Copolymerization of Hepta-1,6-diene with Ethylene Catalyzed by Cobalt Complexes
  Macromol. Rapid Commun. 2008, 29, 1932-1936. (cover picture paper: PDF)
• Guan-Yeow Yeap, Chin-Hin Ong, Daisuke Takeuchi, Masaki Kakeya, Kohtaro Osakada, Wan Ahmad Kamil Mahmood, Ono Atsuko, Volkmar Vill
  Synthesis and molecular structure of asymmetric 2,2'-(4-(alkyloxy)-1,3-phenylene)bis(1-(4-substitutedphenyl)diazene): Crystal structure of 2,2'-(4-(octyloxy)-1,3-phenylene)bis(1-(4-chlorophenyl)diazene)
  J. Mol. Struct.. 2008, 882, 1-8.
• Daisuke Takeuchi, Akihisa Inoue, Fujio Ishimaru, Kohtaro Osakada
  Living Ring-Opening Polymerization of 2-Alkoxy-1-methylenecyclopropanes Initiated by Pd Complexes
  Macromolecules 2008, 41, 6339-6346.
• Guan-Yeow Yeap, Wan-Sinn Yam, Masato M. Ito, Yumika Takahashi, Daisuke Takeuchi, Masaki Kakeya, Kohtaro Osakada, Yoshiyuki Nakamura, Wan Ahmad Kamil Mahmood, Peng-Lim Boey, Shafida Abd Hamid, Ewa Gorecka
  Synthesis and Phase Behaviour of Some New Isoflavone Derivatives
  Ferroelectrics 2008, 365, 65-77.
• Toshiaki Taira, Yuji Suzaki, and Kohtaro Osakada
  Pd(II) and Pt(II) Complexes with Amphiphilic Ligands: Formation of Micellesand [5]Rotaxanes with α-Cyclodextrin in Aqueous Solution
  Chem. Asian J. 2008, 3, 895-902.
• Guan-Yeow Yeap, Wan-Sinn Yam, Daisuke Takeuchi, Kohtaro Osakada, Ewa Gorecka, Wan Ahmad Kamil Mahmood, Peng-Lim Boey, and Shafida Abd Hamid
  Synthesis, Thermal Stabilities and Anisotropic Properties of Some New Isoflavone-based Esters 7-Decanoyloxy-3-(4’-substitutedphenyl)-4H-1-benzopyran-4-ones
  Liq. Cryst. 2008, 35, 315-323.
• Guan-Yeow Yeap, Wan-Sinn Yam, Daisuke Takeuchi, Masaki Kakeya, and Kohtaro Osakada
  Synthesis and Phase Behaviour of New Isoflavone Derivatives: Crystal Structure of 7-Hexyloxy-3-[4’-(3-methylbutyloxy)phenyl]-4H-1-benzopyran-4-one
  Mol. Cryst., Liq. Cryst. 2008, 482, 87-102.
• Guan-Yeow Yeap, Tiang-Chuan Hng, Wan Ahmad Kamil Mahmood, Ewa Gorecka, Daisuke Takeuchi, and Kohtaro Osakada
  Novel Nonsymmetric Trimeric Liquid Crystals Exhibiting Glassy Nematic State at Low Temperatures
  Mol. Cryst., Liq. Cryst. 2008 487, 135-152.
• Atsunori Mori, Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, and Munetaka Akita
  Electrophilic Substitution of Platinum(II) Complexes with Thiophene Derivatives
  Chem. Lett. 2008, 37, 542-543.
• Makoto Tanabe, Daisuke Ito, and Kohtaro Osakada
  Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si-H Bond Cleavage and Formation
  Organometallics 2008 27, 2258-2267.
• David E. Herbert, Makoto Tanabe, Sara C. Bourke, Alan J. Lough, and Ian Manners
  Strain-Controlled, Photochemically, or Thermally Promoted Haptotropic Shifts of Cyclopentadienyl Ligands in Group 8 Metallocenophanes
  J. Am. Chem. Soc. 2008, 130, 4166-4176.
• Makoto Tanabe, Kohji Mutou, Neli Mintcheva, Kohtaro Osakada
  Preparation and NMR Studies of Palladium Complexes with a SilsesquioxanateLigand
  Organometallics 2008 27, 519-523.
• Toshiaki Taira, Yuji Suzaki, Kohtaro Osakada
  [5]Rotaxanes Composed of α-Cyclodextrin and Pd or Pt Complexes with Alkylbipyridinium Ligands
  Chem. Lett. 2008, 37, 182-183.

2007年

総説等

• 竹内　大介
  新しい合成法による両親媒性ポリマーの界面活性分子としての応用
  表面
• 須崎　裕司
  「分子で作るボロメアンの環とソロモンの結び目」
  Bull. Jpn. Soc. Coord. Chem (錯体化学会誌), 2007, 50, 40-41.
• 竹内 大介, 朴 世訓, 岡田 健史, 松浦 龍一, 小坂田 耕太郎
  「後期遷移金属触媒によるジエンの新しい精密環化重合」
  高分子論文集　2007, 64, 597.
• 田邊真，小坂田耕太郎(著者－共著) 第V編6章　シルセスキオキサン金属錯体の合成
  「シルセスキオキサンの合成と応用展開」　伊藤真樹編，シーエムシー出版，2007, p 301-311
• 竹内大介，小坂田耕太郎
  「錯体触媒の特色を生かした新しい高分子合成」
  ファインケミカル 2007, 36(6), 42-49.
• 石川　尚子
  ポスター賞を受賞して　1PA043
  「橋架けゲルミレン配位子をもつ平面型四核錯体の構造と生成機構の解明」
  Bull. Jpn. Soc. Coord. Chem. 2007, 49, 52-54.
• 須崎裕司，小坂田耕太郎
  「光照射によって駆動する分子シャトル」
  化学，2006, 62(2), 68-69.
• Yuji Suzaki, Takeyoshi Yagyu, and Kohtaro Osakada
  Transmetalation of Arylpalladium and Platinum Complexes. Reaction Mechanismand Application to Macrocycle Synthesis
  J. Organomet. Chem. 2007, 692, 326-342.

原著論文

• Doo Kyung Moon, Ju-Young Yun, Kohtaro Osakada, Takaki Kanbara, and Takakazu Yamamoto
  Synthesis of Random Copolymers of Pyrrole and Aniline by Chemical Oxidative Polymerization,
  Mol. Cryst., Liq. Cryst. 2007, 177-185.
• Haritha Buchammagari, Yoshitake Toda, Masahiro Hirano, Hideo Hosono, Daisuke Takeuchi, Kohtaro Osakada
  Room Temoperature-stable Electride as a Synthetic Organic Reagent: Application to Pinacol Coupling Reaction in Aqueous Media
  Org. Lett. 2007, 9, 4287-4289.
• Takeshi Okada, Sehoon Park, Daisuke Takeuchi, Kohtaro Osakada
  Pd Complex-Catalyzed Polymerization of Dienes Involving Chain-Walking Isomerization of Growing Polymer End. Precise Synthesis of Polymers Composed of Polymethylene and Five-Membered Ring Units
  Angew. Chem., Int. Ed. 2007, 46, 6141-6143. (inside cover picture paper)
• Daisuke Takeuchi, Ryuichi Matsuura, Sehoon Park, Kohtaro Osakada
  Cyclopolymerization of 1,6-Heptadienes Catalyzed by Iron and Cobalt Complexes: Synthesis of Polymers with trans- or cis-Fused 1,2-Cyclopentanediyl Groups Depending on the Catalyst
  J. Am. Chem. Soc. 2007, 129, 7002-7003.
• Yuji Suzaki and Kohtaro Osakada
  Ferrocene-Containing [2]- and [3]Rotaxanes. Preparation via End-Capping Cross-Metathesis Reaction and Their Electrochmical Properties
  Dalton Trans. 2007, 2376-2383. (cover picture paper)
• Masaki Horie, Takafumi Sassa, Daisuke Hashizume, Yuji Suzaki, Kohtaro Osakada, and Tatsuo Wada
  A crystalline Supramolecular Switch: Controlling the Optical Anisotropy via the Collective Dynamic Motion of Molecules
  Angew. Chem., Int. Ed. 2007, 46, 4983-4986.
• Yuji Suzaki, Toshiaki Taira, and Kohtaro Osakada
  Preparation of a Zwitterionic Trichloroplatinum(II) Complex with an Alkylbipyridinum Ligand and Its Reaction in Dmso-d₆ Solution.
  Transit. Met. Chem. 2007, 32, 753-756
• Makoto Tanabe, Akane Mawatari, and Kohtaro Osakada
  Dipalladium Complex with Bridging Silylene Ligands, [{Pd(dmpe)}₂(µ-SiPh₂)₂], Formed via Dimerization of Bis(silyl)palladium Complex
  Organometallics 2007, 26, 2937-2940.
• Yuji Suzaki, Toshiaki Taira, Daisuke Takeuchi, and Kohtaro Osakada
  Competing Supramolecular Assembly of Amphiphiles to Form Micelles or Pseudorotaxanes
  Org. Lett. 2007, 9, 887-890.
• Neli Mintcheva, Makoto Tanabe, and Kohtaro Osakada
  Arylpalladium Complexes with a Silsesquioxanate Ligand. Preparation and Structures in Solid State and in Solution
  Organometallics 2007, 26, 1402-1410.
• Makoto Tanabe, Daisuke Ito, and Kohtaro Osakada
  Diplatinum Complexes with Bridging Silyl Ligands. Si-H Bond Activation of µ-Silyl Ligand Leading to a New Platinum Complex with Bridging Silylene and Silane Ligands
  Organometallics 2007, 26, 459-462.

2006年

書籍等

• Kohtaro Osakada
  "Comprehensive Organometallic Chemistry III, Vol. 8" Eds by R. H. Crabtree and D. M. P. Mingos. Chapter 8 Platinum σ-Bond Complexes, 445-610.　
• 須崎裕司，小坂田耕太郎(著者－共著)
  第2章　ロタキサン・カテナン
  「環状・筒状超分子新素材の応用技術」　高田十志和編，シーエムシー出版，2006 p 7-19

総説等

• 小坂田　耕太郎，田邊　真
  遷移金属による有機ケイ素化合物の活性化　―Si－H基の反応に関する最近の研究―
  ケイ素化学協会誌　2006, (23), 9-13.
• Kohtaro Osakada, Tatsuaki Sakano, Masaki Horie, and Yuji Suzaki
  Functionalized ferrocenes: Unique properties based on electronic communication between amino group of the ligand and Fe center
  Coord. Chem. Rev. 2006, 250, 1012-1022
• 小坂田　耕太郎，竹内　大介
  錯体触媒を用いるエチレンの共重合
  ポリファイル, 2006, (2), 29-32.

原著論文

• Masaki Horie, Tatsuaki Sakano, and Kohtaro Osakada
  Preparation and Electrochemical Properties of SAM of Alkanethiols Functionalized with 2-Aza[3]ferrocenophane on Gold Electrode
  J. Organomet. Chem., 2006, 691, 5935-5945.
• Yuji Suzaki, Toshiaki Taira and Kohtaro Osakada
  Irreversible and Reversible Formation of [2]Rotaxane Containing Platinum(II) Complex with an N-Alkyl Bipyridinium Ligand as the Axis Component(cover picture paper)
  Dalton Trans. 2006, 5345-5351.
• Takeshi Umemiya, Daisuke Takeuchi, and Kohtaro Osakada
  Synthesis of Macrocyclic Polyethers via Ru Complex-Catalyzed Metathesis Cyclization and Their Use as the Ring Component of Rotaxanes
  J. Organomet. Chem., 2006, 691, 5260-5266
• Daisuke Takeuchi, Itaru Asano, and Kohtaro Osakada
  Synthesis and Structure of Cyclic Oligo(p-Phenylene oxide)s,(C₆H₄-O)n (n = 6 - 10)
  J. Org. Chem. 2006, 71, 8614-8617.
• Atsushi Sugie, Kei Kobayashi, Yuji Suzaki, Kohtaro Osakada and Atsunori Mori
  Observation of Sequential Electrophilic Substitution of Bromothiophene and Immediate Reductive Elimination of Arylpalladium Complexes
  Chem. Lett. 2006, 35, 1100-1101.
• Yuji Suzaki and Kohtaro Osakada
  Formation, Dynamic Behavior, and Chemical Transformation of Pt Complexes with a Rotaxane-like Structure
  Chem. Asian J. 2006, 1, 331-343.
• Junpei Kuwabara, Daisuke Takeuchi and Kohtaro Osakada
  Early-Late Heterobimetallic Complexes as Initiator for Ethylene Polymerization.Cooperative Effect of Two Metal Centers to Afford Highly Branched Polyethylene
  Chem. Commun. 2006 3815-3817.
• Daisuke Takeuchi, Takeshi Okada, Junpei Kuwabara and Kohtaro Osakada
  Living Alternating Copolymerization of a Methylenecyclopropane Derivative with CO to Afford Polyketone with Dihydrophenanthrene-1,10-diyl Groups
  Macromol. Chem. Phys. 2006, 207, 1546-1555. (cover picture paper)
• Daisuke Takeuchi, Akihisa Inoue, Kohtaro Osakada, Minoru Kobayashi and Kentaro Yamaguchi
  Pd-Complex-Promoted Living Polymerization of 2-alkoxy-1-methylenecyclopropanes. Synthesis of Linear and Cyclic Polymers and Block Copolymers Having Alkoxy and Vinylidene Groups
  Organometallics 2006, 25, 4062-4064.
  9月11日付けでHeart Cutに掲載
• Makoto Tanabe, Guido W. M. Vandermeulen, Wing Yan Chan, Paul W. Cyr, Lawrence Vanderark, David A. Rider and Ian Manners
  Photocontrolled Living Polymerizations
  Nature Mat. 2006, 5, 467-470.
  Chem.＆ Eng. News, 2006, 84(22), 9.
• Neli Mintcheva, Makoto Tanabe and Kohtaro Osakada
  Preparation and Structure of New Phenylplatinum Complexes Containing Silsesquioxane as a Monodentate or Bidentate Ligand
  Organometallics 2006, 25, 3776-3783.
• Yuji Suzaki and Kohtaro Osakada
  Chemical Properties of Mononuclear and Dinuclear Phenylplatinum (II) Hydroxo Complexes with Cod Ligand. Transmetalation of Arylboronic Acid, Coupling of the Phenyl Ligand, and Carbonyation
  Organometallics 2006, 25, 3251-3258.
• Daisuke Takeuchi, Ayami Yasuda, Takeshi Okada, Junpei Kuwabara, Kohtaro Osakada and Katsuhiko Tomooka
  Copolymerization of 7-Methylenebicyclo[4.1.0]heptane with Carbon Monoxide Initiated by Optically Active Pd Complexes
  Helv. Chim. Acta 2006, 89, 1574-1588.
• Yuji Suzaki, Masaki Horie, Tatsuaki Sakano and Kohtaro Osakada
  Structure and Properties of Protonated N-Alkyl-2-aza-[3]ferrocenophane
  J. Organomet. Chem. 2006, 691, 3403-3407.
• Yuji Suzaki and Kohtaro Osakada
  End-capping of Pseudo[2]rotaxane Composed of Alkyl(ferrocenylmethyl)ammonium and Dibenzo[24]crown-8 via Cross Metathsis Reactions
  Chem. Lett. 2006, 35, 374-375.
• Sehoon Park, Daisuke Takeuchi, and Kohtaro Osakada
  Pd Complex-Promoted Cyclopolymerization of Functionalized α,ω-Dienes and Copolymerization with Ethylene to Afford Polymers with Cyclic Repeating Units
  J. Am. Chem. Soc. 2006, 128, 3510-3511.
• Ivayla Pantcheva and Kohtaro Osakada
  Synthesis and Reactivity of a Platinum (II) Complex with a Chelating Dehydro (arylboronic anhydride) Ligand. Transmetalation of Arylboronic Acid
  Organometallics 2006, 25, 1735-1741.
• Makoto Tanabe, Naoko Ishikawa and Kohtaro Osakada
  Preparation and Structure of a New Dipalladium Complex with Bridging Diphenylgermyl Ligands. Diverse Reactivities of Pd(PCy₃)₂ and Pt(PCy₃)₂ toward Ph₂GeH₂
  Organometallics 2006, 25, 796-798.

2005年

総説等

• Kohtaro Osakada and Makoto Tanabe
  Platinum and Palladium Complexes with Metal-Silicon Bonds. New bonding, Structures, and Chemical Properties
  Bull. Chem. Soc. Jpn. (Accounts), 2005, 78, 1887-1898.
• 竹内大介，桑原純平，小坂田耕太郎
  複核重合触媒の効率的合成法およびその重合作用
  接着, 2005, 49, 223-230.

原著論文

• Makoto Tanabe, Sara C. Bourke, David E. Herbert, Alan J. Lough and Ian Manners
  Reversible, Strain-Controlled Haptotropic Shifts of Cyclopentadienyl Ligands in [1]- and [2]Metallocenophanes
  Angew. Chem., Int. Ed. 2005, 44, 5886-5890.
• Daisuke Takeuchi, Kouhei Anada and Kohtaro Osakada
  Copolymerization of Ethylene with Methylenecyclopropanes with Promotd by Cobalt and Nickel Complexes
  Bull. Chem. Soc. Jpn. 2005, 78, 1868-1878.
• Shingo Nakajima, Michinori Sugimoto, Yoshihiko Nakao, Hirofumi Sato, Shigeyoshi Sakaki and Kohtaro Osakada
  Theoretical Study of Silyl-Bridged Dinuclear Palladium (I) and Platinum (I) Complexes.
  M₂(μ-η²-H SiH₂)₂(PH₃)₂ (M = Pd or Pt). New Insight into the Bonding Nature.
  Organometallics 2005, 24, 4029-4038.
• Ivayla Pantcheva, Yasushi Nishihara and Kohtaro Osakada
  Arylplatinum Arylboronato and Hydroxo Complexes. Relevanc to Transmetalation of Arylboronic Acids with Pt Complexes
  Organometallics 2005, 24, 3815-3817.
• Masaki Horie, Yuji Suzaki and Kohtaro Osakada
  Chemical and Electrochemical Formation of Pseudorotaxanes Composed of Alkyl(ferrocenylmethyl)ammmonium and Dibenzo[24]crown-8
  Inorg. Chem. 2005, 44, 5844-5853.
• Masumi Itazaki, Osamu Kitami, Makoto Tanabe, Yasushi Nishihara and Kohtaro Osakada
  Hexanuclear Pt Complexes Composed of Two Cyclic Triplatinum Units Connected with 1,4-Diphenylene and 1,1-Ferrocenylene Spacer
  J. Organomet. Chem. 2005, 690, 3957-3962.
• Masumi Itazaki, Yasushi Nishihara, Hisami Takimoto, Chikako Yoda and Kohtaro Osakada
  Ring-opening Isomerization of Methylenecyclopropanes Catalyzed by Hydridorhodium(I) Complexes
  J. Mol. Catal. A-Chem. 2005, 241, 65-71.
• Masumi Itazaki, Yasushi Nishihara and Kohtaro Osakada
  Preparation of Pd(PPh₂H)₂(PPh₃)₂ and its Role as a Precursor of a Dinuclear Complex with Bridging Phosphide Ligands
  Transit. Met. Chem. 2005, 30, 828-830.
• Yasushi Nishihara, Chikako Yoda, Masumi Itazaki and Kohtaro Osakada
  Selective C-C Bond Activation of 2-Aryl-1-methylenecyclopropanes Promoted by Ir(I) and Rh(I) Hydrido Complexes. Mechanisms of Ring-opening Isomreization of the Strained Molecules
  Bull. Chem. Soc. Jpn. 2005, 78, 1469-1480.
• Daisuke Takeuchi and Kohtaro Osakada
  Alternating Copolymerization of Ethylene with Methylenebicyclo[4.1.0]heptane Promoted Promoted by Cobalt Complex. Highly Regulated Structure and Thermal Reaarangement of the Obtained Polymer
  Macromolecules 2005, 38, 1528-1530.
• Junpei Kuwabara, Daisuke Takeuchi and Kohtaro Osakada
  Zr/Zr and Zr/Fe Dinuclear Complexes with Flexible Briodging Ligand. Preparation by Olefin Metathesis Reaction of the Mononuclear Precursors and Properties as Properties as Polymerization Catalyst
  Organometallics 2005, 24, 2705-2712.
• Makoto Tanabe, Masumi Itazaki, Osamu Kitami, Yasushi Nishihara and Kohtaro Osakada
  Dinuclear Pt(II) and Pd(I) Complexes with Bridging PPh₂ Ligands from the Reaction of PPh₂H with Zero-valent Complexes of These Metals
  Bull. Chem. Soc. Jpn. 2005, 78, 1288-1290.
• Tatsuaki Sakano, Masaki Horie, Kohtaro Osakada and Hidenobu Nakao
  Azaferrocenophane with Azobenzene-containing Ligand. Cis-trans Isomerization of the Azobenzene Group Influenced by Redox of Fe Center via Intramolecular Electron Transfer.
  Eur. J. Inorg. Chem. 2005, 644-652.
• Kohtaro Osakada, Hiroyuki Onodera and Yasushi Nishihara
  Diarylpalladium Complexes with a Cis Structure. Formation via Transmetalation of Arylbronic Acid with an Phenyliodopalladium Complex and Intramolecular Coupling of the Aryl Ligands Affording Unsymmetrical Biaryls
  Organometallics 2005, 24(2), 190-192.
• Tomoaki Tanase, Eri Goto, Hiroe Takenaka, Takashi Horiuchi, Yasuhiro Yamamoto, Junpei Kuwabara and Kohtaro Osakada
  Cage-Type Hexanuclear Platinum (0) Clusters with Diphosphine and Isocycnide Ligands Enacpsulating Two Mercuri (0) Atoms
  Organometallics, 2005, 24(2), 234-244.
• Junpei Kuwabara, Daisuke Takeuchi and Kohtaro Osakada
  Synthesis and Properties of Zr-Co Heterodinuclear Complexes with a Bridging Bis(cyclopentadienyl) Ligand
  J. Organomet. Chem. 2005, 690, 269-275.
• Junpei Kuwabara, Daisuke Takeuchi and Kohtaro Osakada
  Association of trans-[PdCl₂(NH=CPh₂-kN)₂] via Intermolecular N-H…Cl Hydrogen Bonding in the Solid State and in Solution.
  Bull. Chem. Soc. Jpn. 2005, 4, 668-670.

2004年

• Kohtaro Osakada, Daisuke Takeuchi
  Copolymerization of Carbon Monoxide with Cyclic Compounds Catalyzed by Transition Metal Complexes (総説).
  Catalysis Survey from Asia 2004, 8, 199-209.
• Kohtaro Osakada, Daisuke Takeuchi
  Coordination Polymerization of Dienes, Allenes, and Methylenecyclopropanes (総説).
  Adv. Polym. Sci. 2004, 171, 137-194 .
• M. Tanabe, I Manners
  Photolytic Living Anionic Ring-Opening Polymerization (ROP) of Silicon-Bridged [1]Ferrocenophanes via an Iron-Cyclopentadienyl Bond
  Cleavage Mechanism
  J. Am. Chem. Soc. 2004, 126, 11434-11435.
• Makoto Minato, Susumu Hiratsuka, Ryoko Sekimizu, Takashi Ito, Kohtaro Osakada
  Formation of an h³-Allyl and a Cyclic g-Hydroxyalkyl Complex of Molybdenum from Reaction of MoH₂(h⁵-cyclopentadienyl)₂ with Homoallyl Alcohol
  J. Organomet. Chem. 2004, 689, 1025-1028.
• Junpei Kuwabara, Daisuke Takeuchi, and Kohtaro Osakada
  Preparation and Properties of Cp₂Zr(μ-N=CAr₂)₂PdCl(Me), New Zr/Pd Heterobimetallic Complexes with Bridging Alkylideneamido Ligands
  Organometallics 2004, 23, 5092-5095.
• Masumi Itazaki, Chikako Yoda, Yasushi Nishihara, and Kohtaro Osakada
  C-C and C-H Bond Activation of Dialkylmethylenecyclopropane Promoted by Rhodium and Iridium Complexes. Preparation and Structures of M(η¹:μ²-CH₂CR₂CH=CH₂)(CO)(PPh₃)₂ and trans-M(CH=CHCMeR₂)(CO)(PPh₃)₂ (M = Rh, Ir, R = CH₂CH₂Ph)
  Organometallics 2004, 23, 5402-5409.
• Yuji Suzaki and Kohtaro Osakada
  Transmetalation of Phenylplatinum (II) Complex. Isolation and Characterization of a Dinuclear Intermediate in Intermolecular Phenyl Ligand Transfer
  Organometallics 2004, 23, 5081 -5084.
• Tetsuyuki Yamada, Makoto Tanabe, Kohtaro Osakada, and Yong-Joo Kim
  Palladium-Platinum Heterobimetallic Complexes with Bridging Silicon Ligands. Structure and Reaction with Isonitrile to Afford a Platinacyclopentane Containing Si, N, and C Atoms
  Organoemtallics 2004, 23, 4771- 4777.
• Yasushi Nishihara, Kyoko Nara, Yasuhiro Nishide, Kohtaro Osakada
  Cationic Rh Complexes with Novel Spiro Tetraarylpentaborate Anions Prepared from Arylboronic Acids and Aryloxorhodium Complexes
  Dalton Trans. 2004, 9, 1366-1375.
• Daisuke Takeuchi, Kouhei Anada, and Kohtaro Osakada
  Cobalt-Complex-Catalyzed Copolymerization of Ethylene with 2-Aryl-1-methylenecyclopropanes. First Alternating Copolymer of Ethylene and Vinyl Monomers Having Polar Functional Group
  Angew. Chem., Int. Ed. Engl., 2004, 43, 1233-1235.
  
• Masumi Itazaki, Yasushi Nishihara, and Kohtaro Osakada
  Syntheses of Dinuclear and Trinuclear Hydridoplatinum Complexes with Bridging Phosphido Ligands [Pt₂H₂(μ-PR₂)₂(PEt₃)₂] (R = ^tBu, Ph) and [Pt₃H₂(μ-PPh₂)₄(PEt₃)₂]. Characterization of the Triangular Intermediate [Pt₃H(μ-PPh₂)₃(PEt₃)₃] and Its Chemical Properties
  Organometallics 2004, 23, 1610-1621.
• Kohtaro Osakada and Hidetake Ishii
  Solid-Gas Reaction of CO with Aryloxide Rhodium(I) Complexes. Stepwise Formation of Vaska-type Complexes
  Inorg. Chim. Acta (Topical Issue of Rh and Ir Componds) 2004, 357, 3007.
• Masaki Horie, Yuji Suzaki, Kohtaro Osakada
  Formation of Pseudorotaxne Induced by Electrochemical Oxidation of Ferrocene-containing Axis Molecule in the Presence of Crown Ether
  J. Am. Chem. Soc., 2004, 126, 3684-3685.
• Makoto Tanabe and Kohtaro Osakada
  Insertion of Alkynes into the Pt-Si Bond of Silylplatinum Complexes Leading to Formation of 4-Sila-3-platinacyclobutenes and 5-Sila-2-platina-1,4-cyclohexadienes
  Chem. Eur. J 2004, 10, 416-424
• Yuji Suzaki, Kohtaro Osakada
  Intermolecular Phenyl Ligand Transfer of Pt(II) and Pd(II) Complexes with Bidentate Ligand
  Bull. Chem. Soc. Jpn. 2004, 77, 139-145.
• Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada
  Synthesis and Structural Characterization of the First Unsymmetrical Diarylpalladium Complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, Derived from Transmetallation between 2,4,6-Trifluorophenylboronic Acid and trans-Pd(C₆F₅)I(PEt₃)₂
  Chem. Commun. 2004, 192-193.
• Junpei Kuwabara, Daisuke Takeuchi, Kohtaro Osakada
  MAO-Catalyzed Friedel-Crafts Reactions of Toluene with Chloroalkanes and with Propylene
  J. Mol. Catal. A. 2004, 208, 39-44.
• Masaki Horie, Tatsuaki Sakano, Kohtaro Osakada, Hidenobu Nakao
  A New Azaferrocenophane with an Azobenzene-Containing Ligand. Remote Control of Photoisomerization of the Azobenzene Group by Redox of the Iron Center
  Organometallics 2004, 23, 18-20.

2003年

• 小坂田耕太郎，竹内大介
  コバルト錯体によるエポキシドと一酸化炭素との共重合(総説).
  接着, 2003, 47, 252-256
• Kohtaro Osakada
  Transmetalation (著書－共著)
  Current Methods in Inorganic Chemistry Vol. 3, Elsevier
  Eds by Akio Yamamoto and Hideo Kurosawa, 2003, 233-291.
• 小坂田耕太郎
  錯体化学－基礎と最近の話題－改訂版 (著書－共著)
  2003, 101-122.
• Sunwook Kim, Daisuke Takeuchi, Kohtaro Osakada
  Pd Complex-catalyzed Ring-opening Polymerisation of 2-Aryl-1-methylenecyclopropanes Perspectives in Organometallic Chemistry,
  C. G. Screttas, B. R. Steele eds; Royal Society of Chemistry (Proceeding of ICOMC) 2003, 306-317
• Makoto Tanabe, Tetsuyuki Yamada, Kohtaro Osakada
  Pt-Pd Heterodinuclear and Pd-Pd or Pt-Pt Dinuclear Complexes with Bridging Diphenylsilyl Ligands
  Organometallics 2003, 22, 2190-2192.
• Yuji Suzaki, Kohtaro Osakada
  Cyclization of Dinuclear Aryl- and Aroylpalladium Complexes with the Metal Centers Tethered by an Oligo(ethylene oxide) Chain. Intramolecular Transmetalation of the Cationic Dinuclear Arylpalladium Complexes
  Organometallics 2003, 22, 2193-2195.
• Daisuke Takeuchi, Junpei Kuwabara, Kohtaro Osakada
  Reaction of AlMe₃ with Heterobimetallic Zr/Rh Complexes Having a C₅H₄-CMe₂-Ind (or C₅H₄-CMe₂-C₅H₄) Ligand. Formation of Complexes with a Zr-Indenyl (or Zr-Cyclopentadienyl) σ-Bond
  Organometallics 2003, 22, 2305-2311.
• Daisuke Takeuchi, Ayami Yasuda, Kohtaro Osakada
  Pd Complex-Catalyzed Copolymerization of a Bicyclic Methylenecyclopropane with Carbon Monoxide to Afford a New Polyketone
  Dalton Trans., , 2003, 2029-2035.
• Atsunori Mori, Akitoshi Sekiguchi, Kentaro Masui, Tomohiro Shimada, Masaki Horie, Kohtaro Osakada, Masuki Kawamoto, Tomiki Ikeda
  Facile Synthesis of 2,5-Diarylthiazoles via Palladium-Catalyzed Tandem C-H Substitutions. Design of Tunable Light Emission and Liquid Crystalline Characteristics
  J. Am. Chem. Soc. 2003, 125, 1700-1701.
• Yasumasa Takenaka, Kohtaro Osakada, Makoto Nakano, Tomiki Ikeda
  Liquid Crystalline Polyketone Prepared from Allene Having an Azobenzene Substituent and Carbon Monoxide.
  Macromolecules 2003, 36, 1414-1416.
• Makoto Tanabe, Kohtaro Osakada
  Rh-Pt Heterobimetallic and Diplatinum Complexes with Bridging Silyl and Silylne Ligands.
  Inorg. Chim. Acta 2003, 350, 201-208.
• Makoto Tanabe, Masaki Horie, Kohtaro Osakada
  Preparation, Structures, and Electrochemical Properties of Silaplatinacyclohexadienes with Ferrocenyl Pendant Groups.
  Organometallics 2003, 22, 373-376.
• Sunwook Kim, Daisuke Takeuchi, Kohtaro Osakada
  Ring-Opening Copolymerization of 2-Aryl-1-methylenecyclopropanes with Carbon Monoxide Initiated by Pd-bpy Complexes
  Macromol. Chem. Phys 2003, 204, 666-673.

2002年

• Takeuchi, Daisuke; Sakaguchi, Yoshihiko; Osakada, Kohtaro.
  Alternating copolymerization of propylene oxide with carbon monoxide catalyzed by Co complex and Co/Ru complexes.
  Journal of Polymer Science, Part A: Polymer Chemistry (2002), 40(24), 4530-4537.
• Takeuchi, Daisuke; Anada, Kouhei; Osakada, Kohtaro.
  Addition polymerization of 2-aryl- and 2-ethoxycarbonyl-1-methylenecyclopropanes promoted by nickel complexes
  Macromolecules (2002), 35(26), 9628-9633.
• Suzaki, Yuji; Yagyu, Takeyoshi; Yamamura, Yuichi; Mori, Atsunori; Osakada, Kohtaro.
  Disproportionation of PtPh(CH₂COMe)(cod) and Conproportionation of PtPh₂(cod) and Pt(CH₂COMe)₂(cod) via Intermolecular Phenyl Ligand Transfer.
  Organometallics (2002), 21(24), 5254-5258.
• Itazaki, Masumi; Nishihara, Yasushi; Osakada, Kohtaro.
  Platinum Complex-Catalyzed Hydrosilylation and Isomerization of Methylenecyclopropane Derivatives. Effect of Structures of the Substrate and Catalyst.
  Journal of Organic Chemistry (2002), 67(20), 6889-6895
• Nishihara, Yasushi; Nara, Kyoko; Osakada, Kohtaro.
  Tetraarylpentaborates, [B₅O₆Ar₄]- (Ar = C₆H₄OMe-4, C₆H₃Me₂-2,6): Their Formation from the Reaction of Arylboronic Acids with an Aryloxorhodium Complex, Structure, and Chemical Properties.
  Inorganic Chemistry (2002), 41(16), 4090-4092.
• Takeuchi, Daisuke; Choi, Jun-chul; Takenaka, Yasumasa; Kim, Sunwook; Osakada, Kohtaro.
  Polymerization of high potential monomers by transition metal complex catalysts.
  Kobunshi Ronbunshu (2002), 59(6), 342-355.
• Yagyu, Takeyoshi; Suzaki, Yuji; Osakada, Kohtaro.
  Chemical Properties of Cationic Phenylplatinum(II) Complexes with a 2,2'-Bipyridine Ligand. Insertion of CO and Allene into the Pt-C Bond and Oxidative Addition of MeI.
  Organometallics (2002), 21(10), 2088-2094.
• Tanabe, Makoto; Osakada, Kohtaro.
  Structure of 4-Sila-3-platinacyclobutene and Its Formation via Pt-Promoted γ-Si-H Bond Activation of 3-Sila-1-propenylplatinum Precursor.
  Journal of the American Chemical Society (2002), 124(17), 4550-4551.
• Takeuchi, Daisuke; Osakada, Kohtaro.
  Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groups.
  Chemical Communications (2002), 6, 646-647.
• Nishihara, Yasushi; Itazaki, Masumi; Osakada, Kohtaro.
  Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane.
  Tetrahedron Letters (2002), 43(11), 2059-2061.
• Koike, Tooru; Du, Xiaoli; Mori, Atsunori; Osakada, Kohtaro.
  Silicone as an organosilicon reagent 2. Rhodium-catalyzed conjugate addition of the silicone reagent to α,β-unsaturated carbonyl compounds.
  Synlett (2002), 2, 301-303.
• Fujii, Toshinari; Koike, Tooru; Mori, Atsunori; Osakada, Kohtaro.
  Rhodium-catalyzed addition of aryl- and alkenylsilanediols to aldehydes.
  Synlett (2002), 2, 298-300.
• Fujii, Toshinari; Koike, Tooru; Mori, Atsunori; Osakada, Kohtaro.
  Rhodium-catalyzed hydroarylation and -alkenylation of alkynes with silanediols. A crucial role of the hydroxy group for the catalytic reaction.
  Synlett (2002), 2, 295-297.
• Nishihara, Yasushi; Takemura, Miwa; Osakada, Kohtaro.
  Structure and Properties of Halogeno(hydrido)(triorganosilyl)rhodium (III) Complexes, RhX(H)(SiR1nR23-n)(PPh3)2 (X = Cl, I; R1 = OSiMe3, OEt, R2 = Me). Influence of the Alkoxy Groups and Halo Ligand on Stability and Reactivity of the Complexes.
  Organometallics (2002), 21(5), 825-831.
• Kim, Sunwook; Takeuchi, Daisuke; Osakada, Kohtaro.
  Pd-Catalyzed Ring-Opening Copolymerization of 2-Aryl-1-methylenecyclopropanes with CO to Afford Polyketones via Alternating Insertion of the Two Monomers and C-C Bond Activation of the Three-Membered Ring.
  Journal of the American Chemical Society (2002), 124(5), 762-763.
• Hirano, Masafumi; Osakada, Kohtaro; Nohira, Hiroyuki; Miyashita, Akira.
  Crystal and solution structures of photochromic spirobenzothiopyran. First full characterization of the meta-stable colored species.
  Journal of Organic Chemistry (2002), 67(2), 533-540.

2001年

• Atsunori Mori, Yasunori Danda, Tooru Fujii, Kazunori Hirabayashi, Kohtaro Osakada
  Hydroxorhodium Complex Catalyzed Carbon-carbon Bond Forming Reactions of Silanediol with α,β-Unsaturated Carbonyl Compounds.
  J. Am. Chem. Soc. 2001, 123, 10774-10775.
• Makoto Tanabe and Kohtaro Osakada
  Rh-Pt Heterobimetallic Complexes with Bridging Organosilyl Ligands. Dynamic Behavior of the Bridging Ligands in Solution.
  Chem. Lett., 2001, 962-963.
• Yasumasa Takenaka and Kohtaro Osakada
  Rh Complex Catalyzed Alternating Copolymerization of Alkylallene with CO. A Significant Influence of Substituents of the Monomers on Polymerization Rate.
  Macromol. Chem. Phys. 2001, 3571-3578
• Tatsuaki Sakano and Kohtaro Osakada
  Further Investigation of Preparation and Chemical and Electrochemical Properties of N-Substituted 2-Aza-[3]-ferrocenophanes.
  Bull. Chem. Soc. Jpn. 2001, 74, 2059-2065.
• Takeyoshi Yagyu and Kohtaro Osakada
  Vinyl- and Dienylpalladium Complexes Formed via Insertion of Alkyne into Sterically Hindered Pd-Aryl Bond.
  Bull. Chem. Soc. Jpn. 2001, 74, 1435-1436.
• Makoto Tanabe and Kohtaro Osakada
  Double Addition of the Si-H Bonds of Pt(SiHPh₂)₂(Pme₃)₂ to CN Triple Bond to Give Azadisilaplatinacyclobutanes.
  Organometallics 2001, 20, 2118-2120.
• Daisuke Takeuchi, Sunwook Kim and Kohtaro Osakada
  Pd Complex Catalyzed Ring-Opening Polymerization of 2-Aryl-1-methylenecyclopropane to Afford Structurally Regulated Polymers.
  Angew. Chem., Int. Ed. 2001, 40, 2685-2688.
• Yasushi Nishihara, Chikako Yoda, Kohtaro Osakada
  Hydrido-rhodium (I) and -iridium (I) Complex Promoted Ring-Opening Isomerization of Unsymmetrically Substituted Methylenecyclopropanes into 1,3-Dienes. Structures of Intermediates and Reaction Pathways.
  Organometallics 2001, 20, 2124-2126.
• Makoto Tanabe, Hideto Yamazawa, and Kohtaro Osakada
  Four, Five- and Six-membered Silaplatinacycles Obtained Selectively from Reaction of an Arylallene with Pt(SiHPh₂)₂(PMe₃)₂.
  Organometallics, 2001, 20, 4451-4453.
• Ken-ichiro Nishiwaki, Mineto Kobayashi, Takao Takeuchi, Kazumasa Matuoto, Kohtaro Osakada
  Nieuwland Type Catalyst. Investigation of Structure in the Solid State and in Solution and Performance for Dimerization of Acetylene.
  J. Mol. Catal. A, 2001, 175, 73-81.
• Isao Yamaguchi, Hidetake Ishii, Tatsuaki Sakano, Kohtaro Osakada, Takakazu Yamamoto
  Rh and Ru Complexes Catalyzed Condensation of Ferrocene Containing Diols and Dithiols with Diarylsilanes to Give Silaferrocenophanes and Ferrocene Polymers.
  Appl. Organomet. Chem. 2001, 15, 197-203.
• Yasushi Nishihara, Miwa Takemura, Kazutaka Ikegashira, Atsunori Mori, Kohtaro Osakada,
  Reaction of Alkynylsilanes with CuCl in Polar Solvents Leading to Alkynyl Group Transfer from Si to Cu.
  J. Organomet. Chem. 2001, 620, 282-286.
• Neli Mintcheva, Yasushi Nishihara, Atsunori Mori, and Kohtaro Osakada
  Reaction of ArMe₂SiOH with cationic Pt-PPh₃ complexes. Si-C bond activation and formation of a siloxoplatinum complex.
  J. Organomet. Chem. 2001, 629, 61-67.
• Takeyoshi Yagyuu, Makiko Hamada, Kohtaro Osakada, Takakazu Yamamoto
  Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(NN)(solv)]BF₄ (NN = N,N,N′,N′-tetramethylethylenediamine, 2,2′-bipyridine, 4,4′-dimethyl-2,2′-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the PdC Bond.
  Organometallics, 2001, 20, 1087-1101.
• Neli Mintcheva, Yasushi Nishihara, Makoto Tanabe, Kazunori Hirabayashi, Atsunori Mori, and Kohtaro Osakada
  Si-C Bond Activation of Silanol Promoted by Bromoplatinum (II) Complexes in the Presence of Ag(I) Salts. Selective Aryl Group Transmetalation from Si to Pt.
  Organometallics, 2001, 20, 1243-1246.
• Tatsuaki Sakano and Kohtaro Osakada
  Polyacetylenes with Ferrocenophane Pendant Groups. Synthesis by Rh Complex Catalyzed Polyaddition, Chracterization, and the Properties
  Macromol. Chem. Phys. 2001, 202, 1829-1836.